Crystal structures and thermochemistry on phase change materials (n-CnH2n+1NH3)(2)CuCl4(s) (n=14 and 15)
文献类型：期刊论文
| 作者 | He, Dong-Hua1; Di, You-Ying1; Tan, Zhi-Cheng2; Yi, Fang-Fang1; Dan, Wen-Yan1; Liu, Yu-Pu1 |
| 刊名 | solar energy materials and solar cells
 |
| 出版日期 | 2011-10-01 |
| 卷号 | 95期号:10页码:2897-2906 |
| 关键词 | (n-CnH2n+1NH3)(2)CuCl4 (n=14 and 15) X-ray crystallography Phase change materials Adiabatic calorimetry Low-temperature heat capacity Solid-solid phase transition |
| 英文摘要 | crystalline compounds (c14h29nh3)(2)cucl4(s) and (c15h31nh3)(2)cucl4(s) were synthesized. x-ray crystallography was applied to characterize crystal structures of the two compounds. the crystal system is both monoclinic, the space group is both c2/c, and z=4. the lattice potential energies of the title compounds were calculated to be u-pot [(c14h29nh3)(2)cucl4, s]=853.12 kj/mol and u-pot [(c15h31nh3)(2)cucl4, s]=854.93 kj/mol. low-temperature heat capacities of the two compounds were measured by a precision automatic adiabatic calorimeter over the temperature range from 78 to 395 k. the temperatures, molar enthalpies, and entropies of two phase transitions for each of the two complexes were determined to be: for (c14h29nh3)(2)cucl4(s), 342.35 +/- 0.11 k, 76.17 +/- 0.40 kj/mol, and 222.49 +/- 1.20 j/k mol for the first peak; 352.61 +/- 0.09 k, 27.83 +/- 0.27 kj/mol, and 78.92 +/- 0.78 j/k mol for the second peak, and for (c15h31nh3)(2)cucl4(s), they were 345.40 +/- 0.93 k, 62.06 +/- 1.07 kj/mol, and 179.67 +/- 2.63 j/k mol for the first peak; 360.98 +/- 0.25 k, 21.66 +/- 0.76 kj/mol, and 60.00 +/- 2.09 j/k mol for the second peak, respectively. the smoothed heat capacities and thermodynamic functions (h-t(o)-h-298.15(o)) and (delta s-trs(m)=delta h-trs(m)/t-trs) of the two compounds were calculated with an interval of 5 k based on the experimental heat capacities. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; technology ; physical sciences |
| 类目[WOS] | energy & fuels ; materials science, multidisciplinary ; physics, applied |
| 研究领域[WOS] | energy & fuels ; materials science ; physics |
| 关键词[WOS] | thermal-energy storage ; heat-capacity ; transitions |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000293936300027 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142329]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Shandong Prov Key Lab Chem Energy Storage & Novel, Liaocheng 252059, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab & Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | He, Dong-Hua,Di, You-Ying,Tan, Zhi-Cheng,et al. Crystal structures and thermochemistry on phase change materials (n-CnH2n+1NH3)(2)CuCl4(s) (n=14 and 15)[J]. solar energy materials and solar cells,2011,95(10):2897-2906. |
| APA | He, Dong-Hua,Di, You-Ying,Tan, Zhi-Cheng,Yi, Fang-Fang,Dan, Wen-Yan,&Liu, Yu-Pu.(2011).Crystal structures and thermochemistry on phase change materials (n-CnH2n+1NH3)(2)CuCl4(s) (n=14 and 15).solar energy materials and solar cells,95(10),2897-2906. |
| MLA | He, Dong-Hua,et al."Crystal structures and thermochemistry on phase change materials (n-CnH2n+1NH3)(2)CuCl4(s) (n=14 and 15)".solar energy materials and solar cells 95.10(2011):2897-2906. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。