Extraction of Scandium(III) Using Ionic Liquids Functionalized Solvent Impregnated Resins
文献类型：期刊论文
| 作者 | Zhu, Lili1,2; Liu, Yinghui1,2; Chen, Ji1; Liu, Wanfa3 |
| 刊名 | journal of applied polymer science
 |
| 出版日期 | 2011-06-15 |
| 卷号 | 120期号:6页码:3284-3290 |
| 关键词 | solvent impregnated resins scandium(III) Cyanex 923 polymeric supports ionic liquid |
| 英文摘要 | ionic liquids (ils) functionalized solvent impregnated resins (sirs) were prepared using il modified merrified resin as the polymeric supports by impregnation of extractant for extraction of sc(iii). the ils modified merrifield resin were prepared via covalent anchoring of imidazolium salts onto merrifield resin. the polymeric supports with imidazolium chloride group (rcl) and imidazolium hexafluorophosphate group (rpf6) were characterized by ftir, tga, and elemental analysis. it was found that rcl and rpf6 had tunable hydrophilicity and hydrophobicity, different acid stability, and swelling behaviors in solvents. the effect of cyanex 923 extractant or [c(8)mim][pf6] il impregnated on rcl and rpf6 were studied. the results showed cyanex 923 and [c(8)mim][pf6] exhibited stronger affinity to rpf6 than to rcl. rpf6 with cyanex 923 was found to be effective in sc(iii) extraction. the extraction mechanisms of sirs containing rpf6 and cyanex 923 with or without [c(8)mim][pf6] were cation exchange and neutral complexation, respectively. [c(8)mim][pf6] acted as an extraction media and was involved in the cation exchanged extraction reaction. sc(iii) can be selectively separated from tm(iii), yb(iii), and lu(iii) by the sirs. (c) 2011 wiley periodicals, inc. j appl polym sci 120: 3284-3290, 2011 |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | polymer science |
| 研究领域[WOS] | polymer science |
| 关键词[WOS] | acid ; separation ; design |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000288393100020 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142350]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Rare Earth Resource Utilizat, Changchun 130022, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Chem Lasers, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhu, Lili,Liu, Yinghui,Chen, Ji,et al. Extraction of Scandium(III) Using Ionic Liquids Functionalized Solvent Impregnated Resins[J]. journal of applied polymer science,2011,120(6):3284-3290. |
| APA | Zhu, Lili,Liu, Yinghui,Chen, Ji,&Liu, Wanfa.(2011).Extraction of Scandium(III) Using Ionic Liquids Functionalized Solvent Impregnated Resins.journal of applied polymer science,120(6),3284-3290. |
| MLA | Zhu, Lili,et al."Extraction of Scandium(III) Using Ionic Liquids Functionalized Solvent Impregnated Resins".journal of applied polymer science 120.6(2011):3284-3290. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。