Influence of Au particle size on Au/CeO2 catalysts for CO oxidation
文献类型：期刊论文
| 作者 | Tana; Wang, Fagen; Li, Huaju; Shen, Wenjie |
| 刊名 | catalysis today
 |
| 出版日期 | 2011-10-25 |
| 卷号 | 175期号:1页码:541-545 |
| 关键词 | Au/CeO2 Particle size Au-CeO2 interface CO oxidation |
| 英文摘要 | the au particle size dependence of co oxidation on au/ceo2 catalysts was extensively investigated. by keeping the size of ceo2 particle to be about 12 nm, the increasing size of au particle from 3.9 to 7.5 nm caused significant decrease in the intrinsic activity for co oxidation. comparative study on sodium cyanide leaching, which effectively removed the metallic gold particles but retained the cationic gold clusters in the matrix of ceria, revealed that the cationic gold species could catalyze co oxidation only at higher temperatures, confirming the major contribution of the metallic gold particles in the au/ceo2 system. therefore, it is evident that the au-ceo2 interface determined mainly by the size of au particle plays an essential role in achieving the high reactivity. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | water-gas shift ; gold catalysts ; hydrogen-production ; supported gold ; precipitation ; nanoparticles ; reactivity ; oxygen |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000295735400076 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142362]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tana,Wang, Fagen,Li, Huaju,et al. Influence of Au particle size on Au/CeO2 catalysts for CO oxidation[J]. catalysis today,2011,175(1):541-545. |
| APA | Tana,Wang, Fagen,Li, Huaju,&Shen, Wenjie.(2011).Influence of Au particle size on Au/CeO2 catalysts for CO oxidation.catalysis today,175(1),541-545. |
| MLA | Tana,et al."Influence of Au particle size on Au/CeO2 catalysts for CO oxidation".catalysis today 175.1(2011):541-545. |
入库方式： OAI收割
来源：大连化学物理研究所
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