Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions
文献类型：期刊论文
| 作者 | Wang, Lian-Yue1,2; Li, Jun1; Lv, Ying1; Zhang, Heng-Yun1; Gao, Shuang1 |
| 刊名 | journal of organometallic chemistry
 |
| 出版日期 | 2011-10-01 |
| 卷号 | 696期号:20页码:3257-3263 |
| 关键词 | Aerobic oxidation Alcohols PdCl2 N Nanoparticles N-dimethylacetamide |
| 英文摘要 | a new and simple pdcl2/dma catalytic system for the alcohol oxidation has been developed using molecular oxygen as the sole oxidant under mild conditions. the catalytic system could be reused for three runs without significant loss of catalytic activity. a variety of active and non-active alcohols were oxidized to their corresponding carbonyl compounds in good to excellent yields. gas-uptake kinetics for the catalytic system was also investigated. the ca. 1:1 molar ratio of o-2 uptake to product yield is observed, suggesting the in situ formation of h2o2. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, inorganic & nuclear ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | cross-coupling reactions ; molecular-oxygen ; terminal olefins ; palladium ; water ; conversions ; ketones ; green ; convenient ; complexes |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000293999500019 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142376]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Lian-Yue,Li, Jun,Lv, Ying,et al. Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions[J]. journal of organometallic chemistry,2011,696(20):3257-3263. |
| APA | Wang, Lian-Yue,Li, Jun,Lv, Ying,Zhang, Heng-Yun,&Gao, Shuang.(2011).Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions.journal of organometallic chemistry,696(20),3257-3263. |
| MLA | Wang, Lian-Yue,et al."Aerobic alcohol oxidation using a PdCl2/N,N-dimethylacetamide catalyst system under mild conditions".journal of organometallic chemistry 696.20(2011):3257-3263. |
入库方式： OAI收割
来源：大连化学物理研究所
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