Grafting SnCl4 catalyst as a novel solid acid for the synthesis of 3-methylbut-3-en-1-ol
文献类型：期刊论文
| 作者 | Ji, Min1; Li, Xuefeng1,3; Wang, Junhu2; Zhu, Jianmin3; Zhou, Liming3 |
| 刊名 | catalysis today
 |
| 出版日期 | 2011-09-01 |
| 卷号 | 173期号:1页码:28-31 |
| 关键词 | Grafting tin chloride Lewis acid Support effect Prins condensation |
| 英文摘要 | grafting sncl4 on inorganic support as a novel solid acid catalyst was used to catalyze the prins condensation reaction of isobutene with formaldehyde to produce 3-methylbut-3-en-1-ol (mboh). three supports of sio2, sio2-al2o3 and gamma-al2o3 were used to prepare the catalysts, and the structure and acid property of the tin chloride species formed over different supports was investigated. it was found that the sncl4 grafted on sio2 exhibited high activity and selectivity at a low reaction temperature of 100 degrees c, with formaldehyde conversion of 55% and mboh selectivity of 92%. the superior performance of snclx-sio2 catalyst was attributed to its low electron density of tin nucleus and strong lewis acidity. (c) 2011 elsevier b. v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | prins condensation ; aluminum-chloride ; mossbauer ; mcm-41 |
| 收录类别 | SCI ; ISTP |
| 语种 | 英语 |
| WOS记录号 | WOS:000294303400005 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142399]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem, Dalian 116012, Peoples R China 2.Chinese Acad Sci, Lab Aerosp Catalysis & New Mat, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Liaoning Oxichem Grp Co, Liaoyang 111003, Peoples R China |
| 推荐引用方式 GB/T 7714 | Ji, Min,Li, Xuefeng,Wang, Junhu,et al. Grafting SnCl4 catalyst as a novel solid acid for the synthesis of 3-methylbut-3-en-1-ol[J]. catalysis today,2011,173(1):28-31. |
| APA | Ji, Min,Li, Xuefeng,Wang, Junhu,Zhu, Jianmin,&Zhou, Liming.(2011).Grafting SnCl4 catalyst as a novel solid acid for the synthesis of 3-methylbut-3-en-1-ol.catalysis today,173(1),28-31. |
| MLA | Ji, Min,et al."Grafting SnCl4 catalyst as a novel solid acid for the synthesis of 3-methylbut-3-en-1-ol".catalysis today 173.1(2011):28-31. |
入库方式： OAI收割
来源：大连化学物理研究所
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