Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material
文献类型：期刊论文
| 作者 | Zhang, Aiping1,2; Li, Linqing3; Li, Jun1; Zhang, Yi1; Gao, Shuang1 |
| 刊名 | catalysis communications
 |
| 出版日期 | 2011-07-26 |
| 卷号 | 12期号:13页码:1183-1187 |
| 关键词 | Metal-organic frameworks Zeolitic imidazolate frameworks Molecular oxygen Isobutyraldehyde Epoxidation |
| 英文摘要 | co-containing zeolitic imidazolate framework material (co-zif) was prepared and its catalytic performance in the aerobic epoxidation of olefins using isobutyraldehyde as reductant under mild conditions was first studied. co-zif was characterized by xrd, ft-ir and x-ray single-crystal diffraction. it showed good performance in the epoxidation of olefins, with 100% conversion, 98.5% selectivity and 638.3 turnover frequency for the epoxidation of cyclooctene. co-zif could be reused for 5 times without loss of its catalytic activity and the structure of the recovered catalyst was almost unchanged compared to that of the fresh one. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | hydrogen-peroxide ; molecular-oxygen ; styrene oxide ; complexes ; oxidation ; dioxygen ; alkenes |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000292950000002 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142402]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Dalian Polytech Univ, Dalian 116034, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Aiping,Li, Linqing,Li, Jun,et al. Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material[J]. catalysis communications,2011,12(13):1183-1187. |
| APA | Zhang, Aiping,Li, Linqing,Li, Jun,Zhang, Yi,&Gao, Shuang.(2011).Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material.catalysis communications,12(13),1183-1187. |
| MLA | Zhang, Aiping,et al."Epoxidation of olefins with O-2 and isobutyraldehyde catalyzed by cobalt (II)-containing zeolitic imidazolate framework material".catalysis communications 12.13(2011):1183-1187. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。