Influences of alkaline treatment on the structure and catalytic performances of ZSM-5/ZSM-11 zeolites with alumina as binder
文献类型：期刊论文
| 作者 | Li, Xiujie; Wang, Chuanfu; Liu, Shenglin; Xin, Wenjie; Wang, Yuzhong; Xie, Sujuan; Xu, Longya |
| 刊名 | journal of molecular catalysis a-chemical
 |
| 出版日期 | 2011-02-14 |
| 卷号 | 336期号:1-2页码:34-41 |
| 关键词 | Alkaline treatment Alumina binder ZSM-5/ZSM-11 1-Hexene aromatization |
| 英文摘要 | influences of alkaline treatment on the structural properties and catalytic performances of zsm-5/zsm-11 composite zeolites with alumina as binder at different preparation steps were studied in the present investigation. temperature-programmed desorption of ammonium (nh(3)-tpd) and pyridine infrared (py-ir) spectra revealed that alkaline treatment sequences changed both the distribution and amount of the acidities in the zsm-5/zsm-11-al(2)o(3) samples. the mesopores created by alkaline treatment were found beneficial for the diffusion of aromatic molecules, as determined by the xylene-uptake experiments using a tapered element oscillating microbalance (teom). in 1-hexene isomerization and aromatization reactions, the sample after extrusion followed by alkaline treatment exhibited excellent aromatization activity and stability compared with other samples undergoing different treatment sequences. the enhanced catalytic performance could be attributed to the redistribution of acid sites and introduction of more mesopores. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | mfi zeolites ; zsm-5 zeolites ; mesoporosity development ; controlled desilication ; aromatization ; crystals ; posttreatment ; adsorption ; stability ; 1-hexene |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000288481000005 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142413]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xiujie,Wang, Chuanfu,Liu, Shenglin,et al. Influences of alkaline treatment on the structure and catalytic performances of ZSM-5/ZSM-11 zeolites with alumina as binder[J]. journal of molecular catalysis a-chemical,2011,336(1-2):34-41. |
| APA | Li, Xiujie.,Wang, Chuanfu.,Liu, Shenglin.,Xin, Wenjie.,Wang, Yuzhong.,...&Xu, Longya.(2011).Influences of alkaline treatment on the structure and catalytic performances of ZSM-5/ZSM-11 zeolites with alumina as binder.journal of molecular catalysis a-chemical,336(1-2),34-41. |
| MLA | Li, Xiujie,et al."Influences of alkaline treatment on the structure and catalytic performances of ZSM-5/ZSM-11 zeolites with alumina as binder".journal of molecular catalysis a-chemical 336.1-2(2011):34-41. |
入库方式： OAI收割
来源：大连化学物理研究所
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