High Resolution Crossed Molecular Beams Study on the F plus HD -> DF plus H Reaction at Collision Energy of 8.19-18.98 kJ/mol
文献类型：期刊论文
| 作者 | Dong, Wen-rui; Xiao, Chun-lei; Wang, Tao; Dai, Dong-xu; Wang, Xiu-yan; Yang, Xue-ming |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2011-10-01 |
| 卷号 | 24期号:5页码:521-528 |
| 关键词 | F plus HD -> DF plus FH Crossed molecular beam Rydberg tagging |
| 英文摘要 | the crossed beams scattering dynamics of the f+hd -> df+h reaction have been studied at collision energies ranging from 8.19 kj/mol to 18.98 kj/mol using the high resolution h-atom rydberg tagging time-of-flight method. product rotational state-resolved differential cross sections have been measured. most of the df products are backward scattered at low collision energies and then gradually shift to the sideway as the collision energy increases. in addition to the backward and sideway scatterings, we have also observed the df(v'=4) product in the forward direction for the first time for this reaction. the forward scattering df(v=4) product also increases with the collision energy. angular and collision energy dependence of the product energy disposals in different degrees of freedom have been determined. collision energy dependence of the vibrational branching ratios has also been examined. possible dynamical origins of the forward scattering df(v'=4) products were discussed. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | transition-state ; reaction dynamics ; f+h-2 reaction ; nonadiabatic reaction ; f&h2 reaction ; scattering ; resonance ; surface ; mechanism ; sections |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000297139200004 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142414]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Wen-rui,Xiao, Chun-lei,Wang, Tao,et al. High Resolution Crossed Molecular Beams Study on the F plus HD -> DF plus H Reaction at Collision Energy of 8.19-18.98 kJ/mol[J]. chinese journal of chemical physics,2011,24(5):521-528. |
| APA | Dong, Wen-rui,Xiao, Chun-lei,Wang, Tao,Dai, Dong-xu,Wang, Xiu-yan,&Yang, Xue-ming.(2011).High Resolution Crossed Molecular Beams Study on the F plus HD -> DF plus H Reaction at Collision Energy of 8.19-18.98 kJ/mol.chinese journal of chemical physics,24(5),521-528. |
| MLA | Dong, Wen-rui,et al."High Resolution Crossed Molecular Beams Study on the F plus HD -> DF plus H Reaction at Collision Energy of 8.19-18.98 kJ/mol".chinese journal of chemical physics 24.5(2011):521-528. |
入库方式： OAI收割
来源：大连化学物理研究所
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