Low-Temperature Heat Capacities and Standard Molar Enthalpy of Formation of Gramine (C11H14N2)
文献类型：期刊论文
| 作者 | Chen Jingtao1,2; Kong Yuxia1; Di Youying1; Yang Weiwei1; Tan Zhicheng3 |
| 刊名 | chinese journal of chemistry
 |
| 出版日期 | 2011-11-01 |
| 卷号 | 29期号:11页码:2278-2284 |
| 关键词 | alkaloids adiabatic calorimetry low-temperature heat capacity oxygen-bomb combustion calorimetry standard molar enthalpy of formation thermodynamics |
| 英文摘要 | low-temperature heat capacities of gramine (c11h14n2) were measured by a precision automated adiabatic calorimeter over the temperature range from 78 to 401 k. a polynomial equation of heat capacities as a function of temperature was fitted by least squares method. based on the fitted polynomial, the smoothed heat capacities and thermodynamic functions of the compound relative to the standard reference temperature 298.15 k were calculated and tabulated at 5 k intervals. the constant-volume energy of combustion of the compound at t=298.15 k was measured by a precision oxygen-bomb combustion calorimeter as delta(c)u=-(35336.7 +/- 13.9) j center dot g-1. the standard molar enthalpy of combustion of the compound was determined to be ?chm0=-(6163.2 +/- 2.4) kj center dot mol-1, according to the definition of combustion enthalpy. finally, the standard molar enthalpy of formation of the compound was calculated to be;chm0=-(166.2 +/- 2.8) kj center dot mol-1 in accordance with hess law. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000297414100008 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142419]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China 2.Shaanxi Inst Educ, Dept Chem & Chem Engn, Xian 710061, Shaanxi, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Chen Jingtao,Kong Yuxia,Di Youying,et al. Low-Temperature Heat Capacities and Standard Molar Enthalpy of Formation of Gramine (C11H14N2)[J]. chinese journal of chemistry,2011,29(11):2278-2284. |
| APA | Chen Jingtao,Kong Yuxia,Di Youying,Yang Weiwei,&Tan Zhicheng.(2011).Low-Temperature Heat Capacities and Standard Molar Enthalpy of Formation of Gramine (C11H14N2).chinese journal of chemistry,29(11),2278-2284. |
| MLA | Chen Jingtao,et al."Low-Temperature Heat Capacities and Standard Molar Enthalpy of Formation of Gramine (C11H14N2)".chinese journal of chemistry 29.11(2011):2278-2284. |
入库方式： OAI收割
来源：大连化学物理研究所
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