Electrical Conductivity of Solutions of Ionic Liquids with Methanol, Ethanol, Acetonitrile, and Propylene Carbonate
文献类型:期刊论文
作者 | Zhang, Qing-Guo2; Sun, Si-Si1,2; Pitula, Slawomir1; Liu, Qing-Shan1; Welz-Biermann, Urs1,3; Zhang, Jia-Jun4 |
刊名 | journal of chemical and engineering data
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出版日期 | 2011-12-01 |
卷号 | 56期号:12页码:4659-4664 |
英文摘要 | a series of solutions composed of air- and water-stable hydrophobic ionic liquids (ils) [etpy] [tf(2)n], [bupy][tf(2)n], [pepy] [tf(2)n], [etm(4)py] [tf(2)n], and [bum(4)py][tf(2)n] were prepared. the electrical conductivity of the solutions was investigated at t = 298.15 k, respectively. then the electrical conductivity of solutions of [bupy] [tf(2)n] and [hepy][tf(2)n] in acetonitrile/propylene carbonate were investigated at temperature range from (283.15 to 313.15) k. the correlation of concentration and electrical conductivity was fitted according to the empirical casteel-amis (ca) equation. the maximum electrical conductivity was extrapolated by the fitted result. the influence of the successive methylene (-ch(2)-) group and the organic solvent to the electrical conductivity was discussed. the temperature dependence of the electrical conductivity of the solutions, ils [bupy] [tf(2)n] and [hepy][tf(2)n] in acetonitrile/propylene carbonate, was fitted by the empirical vogel-fulcher-tamman (vft) equation at a volume ratio of 50%. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, multidisciplinary ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | physicochemical properties ; low-viscosity ; temperature ; electrolytes ; tetrafluoroborate ; density ; water ; dependence ; diffusion ; mixtures |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000297608800052 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/142471] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, China Ion Liquid Lab, Dalian 116023, Peoples R China 2.Bohai Univ, Dept Chem, Jinzhou 121000, Peoples R China 3.Evonik Degussa Taiwan Ltd, Taipei 10596, Taiwan 4.Atotech China Chem Ltd, Shanghai Qingpu Branch 5399, Shanghai 201707, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang, Qing-Guo,Sun, Si-Si,Pitula, Slawomir,et al. Electrical Conductivity of Solutions of Ionic Liquids with Methanol, Ethanol, Acetonitrile, and Propylene Carbonate[J]. journal of chemical and engineering data,2011,56(12):4659-4664. |
APA | Zhang, Qing-Guo,Sun, Si-Si,Pitula, Slawomir,Liu, Qing-Shan,Welz-Biermann, Urs,&Zhang, Jia-Jun.(2011).Electrical Conductivity of Solutions of Ionic Liquids with Methanol, Ethanol, Acetonitrile, and Propylene Carbonate.journal of chemical and engineering data,56(12),4659-4664. |
MLA | Zhang, Qing-Guo,et al."Electrical Conductivity of Solutions of Ionic Liquids with Methanol, Ethanol, Acetonitrile, and Propylene Carbonate".journal of chemical and engineering data 56.12(2011):4659-4664. |
入库方式: OAI收割
来源:大连化学物理研究所
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