Study on collisional deactivation of O-2((1)Delta(g)) by H-2 and D-2
文献类型：期刊论文
| 作者 | Du, Shuyan; Leng, Jing; Wang, Junhui; Yang, Heping; Sha, Guohe; Zhang, Cunhao |
| 刊名 | chemical physics
 |
| 出版日期 | 2011-05-26 |
| 卷号 | 383期号:1-3页码:83-85 |
| 关键词 | Singlet oxygen Collisional deactivation Hydrogen Deuterium |
| 英文摘要 | the deactivation rate constants of o-2((1)delta(g)) by h-2 and d-2 are respectively measured to be 3.91 +/- 0.12 x 10(-18) cm(3) s(-1) and 1.1 +/- 0.3 x 10(-19) cm(3) s(-1), which agree well with the quantum mechanical calculation by kustrev. their deactivation mechanisms by h-2 and d-2 are analyzed according to the e-v energy transfer model developed by schmidt, indicating that the main deactivation channel for h-2 is o-2((1)delta(g), v = 0 --> (3)sigma(-)(g), v '' = 0) and h-2 (delta v = 2), while that for d-2 is o-2((1)delta(g), v' = 0 --> (3)sigma(-)(g), v '' = 1) and d-20 (delta v = 2), which entirely matches the calculation by kustrev. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical ; physics, atomic, molecular & chemical |
| 研究领域[WOS] | chemistry ; physics |
| 关键词[WOS] | singlet oxygen ; solvent molecules ; spectroscopy ; o2(a1deltag) |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000291027600011 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142492]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Du, Shuyan,Leng, Jing,Wang, Junhui,et al. Study on collisional deactivation of O-2((1)Delta(g)) by H-2 and D-2[J]. chemical physics,2011,383(1-3):83-85. |
| APA | Du, Shuyan,Leng, Jing,Wang, Junhui,Yang, Heping,Sha, Guohe,&Zhang, Cunhao.(2011).Study on collisional deactivation of O-2((1)Delta(g)) by H-2 and D-2.chemical physics,383(1-3),83-85. |
| MLA | Du, Shuyan,et al."Study on collisional deactivation of O-2((1)Delta(g)) by H-2 and D-2".chemical physics 383.1-3(2011):83-85. |
入库方式： OAI收割
来源：大连化学物理研究所
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