Effects of sintering temperature on properties of dual-phase oxygen permeable membranes
文献类型：期刊论文
| 作者 | Li, Qiming1,2; Zhu, Xuefeng1; He, Yufeng1; Cong, You1; Yang, Weishen1 |
| 刊名 | journal of membrane science
 |
| 出版日期 | 2011-02-01 |
| 卷号 | 367期号:1-2页码:134-140 |
| 关键词 | Dual-phase membrane Sintering temperature Oxygen permeation Element transport Grain size |
| 英文摘要 | the effects of sintering temperature on the properties of ce(0.85)sm(0.15)o(3-delta)-sm(0.6)sr(0.4)feo(3-delta) (sdc-ssf) dual-phase membranes were investigated. x-ray diffraction (xrd), scanning electron microscope (sem), energy dispersive x-ray analysis (edx), alternating current impedance and oxygen permeation techniques were employed to study the phase structure, element transport, microstructure, grain size and oxygen permeation through dual-phase membranes sintered at different temperatures. sintering temperature has complex effects on dual-phase membranes compared with single-phase perovskite membranes. xrd and edx analysis results reveal that the surfaces of dual-phase membranes were mainly coated by fluorite oxide with a thickness of about 45 mu m when the membrane was sintered at 1500 degrees c. fluorite grains were gradually transferred from the inner layer to the outer layer with the increase of sintering temperature, which leads to a decrease in electronic conductivity of the membrane surface. the grain size increased with the rising of sintering temperature, which has negatively effect on oxygen permeation when the sintering temperature is higher than 1425 degrees c. (c) 2010 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; technology ; physical sciences |
| 类目[WOS] | engineering, chemical ; polymer science |
| 研究领域[WOS] | engineering ; polymer science |
| 关键词[WOS] | perovskite-type oxides ; partial oxidation ; composite membranes ; air separation ; permeation ; methane ; reactors ; performance ; stability ; syngas |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000286852000017 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142513]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Liaoning Univ Petr Chem Technol, Sch Petrochem Engn, Fushun Liaoning 113001, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Qiming,Zhu, Xuefeng,He, Yufeng,et al. Effects of sintering temperature on properties of dual-phase oxygen permeable membranes[J]. journal of membrane science,2011,367(1-2):134-140. |
| APA | Li, Qiming,Zhu, Xuefeng,He, Yufeng,Cong, You,&Yang, Weishen.(2011).Effects of sintering temperature on properties of dual-phase oxygen permeable membranes.journal of membrane science,367(1-2),134-140. |
| MLA | Li, Qiming,et al."Effects of sintering temperature on properties of dual-phase oxygen permeable membranes".journal of membrane science 367.1-2(2011):134-140. |
入库方式： OAI收割
来源：大连化学物理研究所
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