Photochemistry of the Water Molecule: Adiabatic versus Nonadiabatic Dynamics
文献类型：期刊论文
| 作者 | Yuan, Kaijun1; Dixon, Richard N.2; Yang, Xueming1 |
| 刊名 | accounts of chemical research
 |
| 出版日期 | 2011-05-01 |
| 卷号 | 44期号:5页码:369-378 |
| 英文摘要 | water and light are two common constituents of both the earth's atmosphere and interstellar space. consequently, water photodissoclation is a central component of the chemistry of these environments. electronically excited molecules can dissociate adiabatically (on a single potential energy surface, or pes) or nonadiabatically (with transfer between pess), and water serves as a prototype for understanding these two processes in unimolecular dissodation. in recent years, extensive experimental and theoretical studies have been focused on water photolysis, particularly on the primary product of the dissociation, the oh radical. the use of the high-resolution h-atom rydberg tagging technique, in combination with various vacuum ultra-violet (vuv) sources, has spurred significant advances in water photochemistry. as the excitation energy increases, different excited electronic states of water can be reached, and the mutual interactions between these states increase significantly. in this account, we present the most recent developments in water photodissociation that have been derived from the study of the four lowest electronic excited states. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | multiphoton ionization spectroscopy ; rotational state distributions ; diffuse vibrational-structures ; 2nd absorption-band ; photodissociation dynamics ; dissociation dynamics ; ab-initio ; 121.6 nm ; predissociation dynamics ; quantum state |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000291121900006 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142521]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian, Peoples R China 2.Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England |
| 推荐引用方式 GB/T 7714 | Yuan, Kaijun,Dixon, Richard N.,Yang, Xueming. Photochemistry of the Water Molecule: Adiabatic versus Nonadiabatic Dynamics[J]. accounts of chemical research,2011,44(5):369-378. |
| APA | Yuan, Kaijun,Dixon, Richard N.,&Yang, Xueming.(2011).Photochemistry of the Water Molecule: Adiabatic versus Nonadiabatic Dynamics.accounts of chemical research,44(5),369-378. |
| MLA | Yuan, Kaijun,et al."Photochemistry of the Water Molecule: Adiabatic versus Nonadiabatic Dynamics".accounts of chemical research 44.5(2011):369-378. |
入库方式： OAI收割
来源：大连化学物理研究所
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