Size-Selective Carbon Nanoclusters as Precursors to the Growth of Epitaxial Graphene
文献类型：期刊论文
| 作者 | Wang, Bo1; Ma, Xiufang2,3; Caffio, Marco1; Schaub, Renald1; Li, Wei-Xue2,3 |
| 刊名 | nano letters
 |
| 出版日期 | 2011-02-01 |
| 卷号 | 11期号:2页码:424-430 |
| 关键词 | Graphene rhodium coronene carbon STM DFT nucleation growth |
| 英文摘要 | the nucleation and growth mechanisms of graphene on rh(111) via temperature-programmed growth of c(2)h(4) are studied by scanning tunneling microscopy and spectroscopy, and by density functional theory calculations. by combining our experimental and first-principles approaches, we show that carbon nanoislands form in the initial stages of graphene growth, possessing an exclusive size of seven honeycomb carbon units (hereafter labeled as 7c(6)). these dusters adopt a domelike hexagonal shape indicating that bonding to the substrate is. localized on the peripheral c atoms. smoluchowski ripening is identified as the dominant mechanism leading to the formation of graphene, with the size-selective carbon islands as precursors. control experiments and calculations, whereby coronene molecules, the hydrogenated analogues of 7c(6), are deposited on rh(111), provide an unambiguous structural and chemical identification of the 7c(6) building blocks. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, multidisciplinary ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary ; physics, applied ; physics, condensed matter |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science ; physics |
| 关键词[WOS] | energy-electron-diffraction ; wave basis-set ; tunneling microscope ; surface ; pt(111) ; rh(111) |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287049100021 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142557]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Univ St Andrews, Sch Chem, Scottish Ctr Interdisciplinary Surface Spect, St Andrews KY16 9ST, Fife, Scotland 2.Chinese Acad Sci, Dalian Inst Chem Phys, Ctr Theoret & Computat Chem, Dalian 116023, Peoples R China 3.Chinese Acad Sci, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Bo,Ma, Xiufang,Caffio, Marco,et al. Size-Selective Carbon Nanoclusters as Precursors to the Growth of Epitaxial Graphene[J]. nano letters,2011,11(2):424-430. |
| APA | Wang, Bo,Ma, Xiufang,Caffio, Marco,Schaub, Renald,&Li, Wei-Xue.(2011).Size-Selective Carbon Nanoclusters as Precursors to the Growth of Epitaxial Graphene.nano letters,11(2),424-430. |
| MLA | Wang, Bo,et al."Size-Selective Carbon Nanoclusters as Precursors to the Growth of Epitaxial Graphene".nano letters 11.2(2011):424-430. |
入库方式： OAI收割
来源：大连化学物理研究所
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