Cobalt oxyphosphide as oxygen reduction electrocatalyst in proton exchange membrane fuel cell
文献类型：期刊论文
| 作者 | Wang, Meiri1; Zhang, Huamin1; Zhong, Hexiang1; Ma, Yuanwei1,2 |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2011 |
| 卷号 | 36期号:1页码:720-724 |
| 关键词 | Proton exchange membrane fuel cell Oxygen reduction reaction Pt-free electrocatalyst Cobalt oxyphosphide |
| 英文摘要 | the cobalt oxyphosphides supported on carbon black were prepared using incipient wetness method and characterized by x-ray diffraction (xrd) and transmission electron microscopy (tem). the possibility of their application as the electrocatalyst for oxygen reduction reaction (orr) in proton exchange membrane fuel cell (pemfc) was investigated and the electrocatalytic activities were evaluated by the electrochemical measurements and single cell test, respectively. the electrocatalyst presents attractive catalytic activity towards orr and good stability in acid media and exhibits an onset potential for oxygen reduction as high as 0.69 v (rhe) in h(2)so(4) solution. the maximum power density obtained in a h(2)/o(2) pemfc is 57 mw cm(-2) with co(4)p(2)o(9)/c loading of 1.13 mg cm(-2). no significant performance degradation is observed over 50 h of continuous fuel cell operation. the combination of heteroatom p with nanostructured oxides with high stability, excellent functionality and low cost which are prerequisites for large-scale applications, probably provide a new solution for the critical challenge of finding effective cathode materials for pemfc. (c) 2010 professor t. nejat veziroglu. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | transition-metal sulfides ; o-2 electroreduction ; catalysts ; cathode ; alloy |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000288102700078 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142563]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Proton Exchange Membrane Fuel Cell Key Mat & Tech, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Meiri,Zhang, Huamin,Zhong, Hexiang,et al. Cobalt oxyphosphide as oxygen reduction electrocatalyst in proton exchange membrane fuel cell[J]. international journal of hydrogen energy,2011,36(1):720-724. |
| APA | Wang, Meiri,Zhang, Huamin,Zhong, Hexiang,&Ma, Yuanwei.(2011).Cobalt oxyphosphide as oxygen reduction electrocatalyst in proton exchange membrane fuel cell.international journal of hydrogen energy,36(1),720-724. |
| MLA | Wang, Meiri,et al."Cobalt oxyphosphide as oxygen reduction electrocatalyst in proton exchange membrane fuel cell".international journal of hydrogen energy 36.1(2011):720-724. |
入库方式： OAI收割
来源：大连化学物理研究所
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