Rhodium(III)-Catalyzed Synthesis of Pyridines from alpha,beta-Unsaturated Ketoximes and Internal Alkynes
文献类型：期刊论文
| 作者 | Too, Pei Chui2; Noji, Toshiharu3; Lim, Ying Jie2; Li, Xingwei1; Chiba, Shunsuke2 |
| 刊名 | synlett
 |
| 出版日期 | 2011-12-01 |
| 期号 | 19页码:2789-2794 |
| 关键词 | pyridines oximes alkynes rhodium C-H activation |
| 英文摘要 | a method for the synthesis of highly substituted pyridines from alpha,beta-unsaturated oximes and internal alkynes has been developed using [cp*rhcl2](2)-csopiv as the catalyst system. the present transformation is carried out by a redox-neutral sequence of vinylic c-h rhodation, alkyne insertion, and c-n bond formation of the putative vinyl rhodium intermediate with the oxime nitrogen, where the n-o bond of oxime derivatives could work as an internal oxidant to maintain the catalytic cycle. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | c-h bond ; one-pot synthesis ; catalyzed oxidative coupling/cyclization ; highly functionalized pyridines ; aromatic imines ; substituted pyridines ; ortho-alkylation ; carbon-hydrogen ; ring-expansion ; vinyl azides |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000297847700004 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142586]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore 3.Tohoku Univ, Grad Sch Pharmaceut Sci, Aoba Ku, Sendai, Miyagi 9808578, Japan |
| 推荐引用方式 GB/T 7714 | Too, Pei Chui,Noji, Toshiharu,Lim, Ying Jie,et al. Rhodium(III)-Catalyzed Synthesis of Pyridines from alpha,beta-Unsaturated Ketoximes and Internal Alkynes[J]. synlett,2011(19):2789-2794. |
| APA | Too, Pei Chui,Noji, Toshiharu,Lim, Ying Jie,Li, Xingwei,&Chiba, Shunsuke.(2011).Rhodium(III)-Catalyzed Synthesis of Pyridines from alpha,beta-Unsaturated Ketoximes and Internal Alkynes.synlett(19),2789-2794. |
| MLA | Too, Pei Chui,et al."Rhodium(III)-Catalyzed Synthesis of Pyridines from alpha,beta-Unsaturated Ketoximes and Internal Alkynes".synlett .19(2011):2789-2794. |
入库方式： OAI收割
来源：大连化学物理研究所
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