Pd-Catalyzed Asymmetric Hydrogenation of C=C Bond of alpha,beta-Unsaturated Ketones
文献类型:期刊论文
作者 | Wang, Duo-Sheng1; Wang, Da-Wei1; Zhou, Yong-Gui1,2 |
刊名 | synlett
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出版日期 | 2011-04-01 |
期号 | 7页码:947-950 |
关键词 | palladium hydrogenation unsaturated ketones SDP ligand |
英文摘要 | homogenous palladium-catalyzed asymmetric hydrogenation of c=c double bond of alpha,beta-unsaturated ketones has been developed by using palladium(ii) trifluoroacetate/(s)-7,7'-bis[ di(4-methoxyphenyl]phosphino)-1,1'-spirobiindane complex [pd(ococf(3))(2)-(s)-an-sdp] as the catalyst under ambient hydrogen pressure and room temperature with up to 89% ee. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, organic |
研究领域[WOS] | chemistry |
关键词[WOS] | beta-unsaturated-ketones ; highly enantioselective hydrogenation ; dynamic kinetic resolution ; chiral palladium catalysts ; spiro diphosphines ; phosphorus ligands ; allylic alcohols ; alpha ; complexes ; imines |
收录类别 | SCI ; IC ; CCR |
语种 | 英语 |
WOS记录号 | WOS:000289411900018 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/142588] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
推荐引用方式 GB/T 7714 | Wang, Duo-Sheng,Wang, Da-Wei,Zhou, Yong-Gui. Pd-Catalyzed Asymmetric Hydrogenation of C=C Bond of alpha,beta-Unsaturated Ketones[J]. synlett,2011(7):947-950. |
APA | Wang, Duo-Sheng,Wang, Da-Wei,&Zhou, Yong-Gui.(2011).Pd-Catalyzed Asymmetric Hydrogenation of C=C Bond of alpha,beta-Unsaturated Ketones.synlett(7),947-950. |
MLA | Wang, Duo-Sheng,et al."Pd-Catalyzed Asymmetric Hydrogenation of C=C Bond of alpha,beta-Unsaturated Ketones".synlett .7(2011):947-950. |
入库方式: OAI收割
来源:大连化学物理研究所
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