Morphological impact of manganese-cerium oxides on ethanol oxidation
文献类型：期刊论文
| 作者 | Li, Huaju1; Qi, Gongshin2; Tana1; Zhang, Xiaojing1; Li, Wei2; Shen, Wenjie1 |
| 刊名 | catalysis science & technology
 |
| 出版日期 | 2011 |
| 卷号 | 1期号:9页码:1677-1682 |
| 英文摘要 | the shape of nanoparticles alters their catalytic performance significantly, but the intrinsic chemical nature of this morphology-dependent phenomenon is still less understood. here, we report that the morphology of mno(x)-ceo(2) nanomaterials that are enclosed by {100} and {111} facets considerably affected the reaction rate and the product selectivity in ethanol oxidation. kinetic investigation revealed that the {100} and the {111} planes had very close apparent activation energies, indicative of the common manganese active species, but the specific reaction rate on the {100} plane was two times greater than that on the {111} plane because of the intrinsically higher oxygen storage capacity. these results evidence that morphology control of binary oxides at the nanometre level could promote their catalytic properties substantially. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | co oxidation ; catalysts ; nanocubes ; nanorods ; temperature ; nanotubes ; surfaces ; alcohols ; shape |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000297073500018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142629]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Gen Motors Global Res & Dev, Chem Sci & Mat Syst Lab, Warren, MI 48090 USA |
| 推荐引用方式 GB/T 7714 | Li, Huaju,Qi, Gongshin,Tana,et al. Morphological impact of manganese-cerium oxides on ethanol oxidation[J]. catalysis science & technology,2011,1(9):1677-1682. |
| APA | Li, Huaju,Qi, Gongshin,Tana,Zhang, Xiaojing,Li, Wei,&Shen, Wenjie.(2011).Morphological impact of manganese-cerium oxides on ethanol oxidation.catalysis science & technology,1(9),1677-1682. |
| MLA | Li, Huaju,et al."Morphological impact of manganese-cerium oxides on ethanol oxidation".catalysis science & technology 1.9(2011):1677-1682. |
入库方式： OAI收割
来源：大连化学物理研究所
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