Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative C-C and C-N Coupling between Oximines and Alkynes
文献类型：期刊论文
| 作者 | Zhang, Xingping1,2; Chen, Dan2,3; Zhao, Miao2; Zhao, Jing1; Jia, Aiqun3; Li, Xingwei2 |
| 刊名 | advanced synthesis & catalysis
 |
| 出版日期 | 2011-03-28 |
| 卷号 | 353期号:5页码:719-723 |
| 关键词 | alkynes arenes isoquinolines oximines rhodium catalysis |
| 英文摘要 | isoquinolines have been synthesized from the redox-neutral dehydrative c-n and c-c cross-coupling between oximines and alkynes using a catalytic amount of (pentamethylcyclopentadiene)rhodium dichloride dimer {[rhcp*cl-2](2)} and cesium acetate (csoac), a process that involves ortho c-h activation of oximines and subsequent functionalization with alkynes. this redox-neutral catalytic isoquinoline synthesis operates under mild conditions, and is insensitive to moisture or air. a broad scope of coupling partners has been established, and a likely mechanism has been suggested. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, applied ; chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | palladium-catalyzed iminoannulation ; h bond-cleavage ; internal alkynes ; terminal acetylenes ; aromatic ketimines ; direct arylation ; asterisk-ir ; activation ; derivatives ; pyridines |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000288701600008 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142653]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Nanjing Univ, Sch Life Sci, State Key Lab Pharmaceut Biotechnol, Nanjing 210093, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Nanjing Univ Sci & Technol, Sch Environm & Biol Engn, Nanjing 210014, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Xingping,Chen, Dan,Zhao, Miao,et al. Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative C-C and C-N Coupling between Oximines and Alkynes[J]. advanced synthesis & catalysis,2011,353(5):719-723. |
| APA | Zhang, Xingping,Chen, Dan,Zhao, Miao,Zhao, Jing,Jia, Aiqun,&Li, Xingwei.(2011).Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative C-C and C-N Coupling between Oximines and Alkynes.advanced synthesis & catalysis,353(5),719-723. |
| MLA | Zhang, Xingping,et al."Synthesis of Isoquinolines via Rhodium(III)-Catalyzed Dehydrative C-C and C-N Coupling between Oximines and Alkynes".advanced synthesis & catalysis 353.5(2011):719-723. |
入库方式： OAI收割
来源：大连化学物理研究所
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