High Resolution Crossed Molecular Beams Study on the F plus HD -> HF plus D Reaction at Collision Energy of 5.43-18.73 kJ/mol
文献类型：期刊论文
| 作者 | Dong, Wen-rui; Xiao, Chun-lei; Wang, Tao; Dai, Dong-xu; Wang, Xiu-yan; Yang, Xue-ming |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2011-10-01 |
| 卷号 | 24期号:5页码:507-514 |
| 关键词 | F plus HD -> HF plus D Crossed molecular beam Rydberg tagging Reactive resonance |
| 英文摘要 | the dynamics of f+hd -> hf+d reaction has been studied at ten collision energies ranging from 5.43 kj/mol to 18.73 kj/mol using high-resolution h/d atom rydberg tagging time-of-flight method. product vibrational and rotational state-resolved differential cross sections have been determined. the intensity of the hf(v'=2) forward products decreases as the collision energy increases, suggesting that the resonance contribution is reduced as the collision energy increases. the forward peak of hf(v'=3) product has also been observed above the threshold of this product channel. product energy disposals in different degrees of freedom have been analyzed. the collision energy dependence of the hf vibrational product branching was also determined. this work presents a comprehensive dynamic picture of this resonance mediated reaction in a wide collision energy regime, providing a good test ground for theoretical understandings of this interesting reaction at higher collision energies. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | transition-state ; f+h-2 reaction ; semiclassical reaction ; reaction dynamics ; exact quantum ; resonance ; scattering ; surface ; probabilities ; spectroscopy |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000297139200002 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142674]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dong, Wen-rui,Xiao, Chun-lei,Wang, Tao,et al. High Resolution Crossed Molecular Beams Study on the F plus HD -> HF plus D Reaction at Collision Energy of 5.43-18.73 kJ/mol[J]. chinese journal of chemical physics,2011,24(5):507-514. |
| APA | Dong, Wen-rui,Xiao, Chun-lei,Wang, Tao,Dai, Dong-xu,Wang, Xiu-yan,&Yang, Xue-ming.(2011).High Resolution Crossed Molecular Beams Study on the F plus HD -> HF plus D Reaction at Collision Energy of 5.43-18.73 kJ/mol.chinese journal of chemical physics,24(5),507-514. |
| MLA | Dong, Wen-rui,et al."High Resolution Crossed Molecular Beams Study on the F plus HD -> HF plus D Reaction at Collision Energy of 5.43-18.73 kJ/mol".chinese journal of chemical physics 24.5(2011):507-514. |
入库方式： OAI收割
来源：大连化学物理研究所
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