Selective Oxidation of Alcohols Catalyzed by a Transition Metal-Free System of NHPI/DDQ/NaNO2
文献类型：期刊论文
| 作者 | Zhou Lipeng1; Zhang Chaofeng1; Fang Tao1; Zhang Bingbing1; Wang Ying1; Yang Xiaomei1; Zhang Wei2; Xu Jie2 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2011 |
| 卷号 | 32期号:1页码:118-122 |
| 关键词 | N-hydroxyphthalimide 2 sodium nitrite selective oxidation oxygen alcohol 3-dichloro-5 6-dicyano-benzoquinone |
| 英文摘要 | a transition metal-free catalyst composed of n-hydroxyphthalimide (nhpi), 2,3-dichloro-5,6-dicyano-benzoquinone (ddq), and nano2 was studied for the selective oxidation of alcohols using o-2 as oxidant. the reaction results showed that this catalyst system can effectively catalyze the oxidation of alcohols to the corresponding aldehydes or ketones. 99% selectivity for benzaldehyde at 65% conversion of benzyl alcohol was obtained at 80 degrees c for 6 h. in the process of reaction, ddq abstracted a hydrogen atom from nhpi to generate a highly reactive pino free radical and hydroquinone. then, pino abstracted a hydrogen atom from alcohols to generate aldehydes or ketones. finally, no from nano2 decomposition in the reaction media catalyzed the oxidation of hydroquinone to quinone by o-2. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | efficient aerobic oxidation ; fine chemicals ; hydrocarbons ; dehydrogenation ; aldehydes ; quinones ; oxygen |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000287107200018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142679]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Zhengzhou Univ, Dept Chem, Zhengzhou 450001, Henan, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou Lipeng,Zhang Chaofeng,Fang Tao,et al. Selective Oxidation of Alcohols Catalyzed by a Transition Metal-Free System of NHPI/DDQ/NaNO2[J]. chinese journal of catalysis,2011,32(1):118-122. |
| APA | Zhou Lipeng.,Zhang Chaofeng.,Fang Tao.,Zhang Bingbing.,Wang Ying.,...&Xu Jie.(2011).Selective Oxidation of Alcohols Catalyzed by a Transition Metal-Free System of NHPI/DDQ/NaNO2.chinese journal of catalysis,32(1),118-122. |
| MLA | Zhou Lipeng,et al."Selective Oxidation of Alcohols Catalyzed by a Transition Metal-Free System of NHPI/DDQ/NaNO2".chinese journal of catalysis 32.1(2011):118-122. |
入库方式： OAI收割
来源：大连化学物理研究所
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