Highly effective CuO/Fe(OH)(x) catalysts for selective oxidation of CO in H-2-rich stream
文献类型：期刊论文
| 作者 | Qiao, Botao1; Wang, Aiqin1; Lin, Jian1; Li, Lin1; Su, Dangsheng2; Zhang, Tao1 |
| 刊名 | applied catalysis b-environmental
 |
| 出版日期 | 2011-06-09 |
| 卷号 | 105期号:1-2页码:103-110 |
| 关键词 | CuO Fe(OH)(x) CuO-Fe2O3 CO oxidation PROX Hydrogen purification |
| 英文摘要 | ferric hydroxide supported copper oxide (cuo/fe(oh)(x)) catalysts were prepared with a simple coprecipitation method and used for selective oxidation of co in h-2-rich gas. the effect of calcination temperatures and cu loadings on the activity as well as the durability of the catalyst was investigated. when the calcination temperature was 200 degrees c and the cu loading was ranging from 7.2 to 17.3 wt%, the catalyst gave the best performance with total conversion of co achievable in a wide temperature window from 110 degrees c to 150 degrees c. to reveal the reason for the high activity of the catalysts, a variety of characterization techniques were employed. the results of xrd and tg-dta indicated that the catalysts were amorphous even after being calcined at 400 degrees c, which gave rise to large surface areas. hrtem and xps examinations indicated that the surface copper species were cu2o with particle size of smaller than 5 nm. in situ drift and ft-ir results showed that the reduction of cu2+ in the composite occurred even below room temperature when exposed to co. the significant reducibility might contribute to the high activity of the catalysts. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; engineering, environmental ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | carbon-monoxide oxidation ; supported gold catalysts ; preferential oxidation ; cuo-ceo2 catalysts ; oxide catalysts ; excess hydrogen ; au catalysts ; temperature ; copper ; h-2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000291907400012 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142682]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany |
| 推荐引用方式 GB/T 7714 | Qiao, Botao,Wang, Aiqin,Lin, Jian,et al. Highly effective CuO/Fe(OH)(x) catalysts for selective oxidation of CO in H-2-rich stream[J]. applied catalysis b-environmental,2011,105(1-2):103-110. |
| APA | Qiao, Botao,Wang, Aiqin,Lin, Jian,Li, Lin,Su, Dangsheng,&Zhang, Tao.(2011).Highly effective CuO/Fe(OH)(x) catalysts for selective oxidation of CO in H-2-rich stream.applied catalysis b-environmental,105(1-2),103-110. |
| MLA | Qiao, Botao,et al."Highly effective CuO/Fe(OH)(x) catalysts for selective oxidation of CO in H-2-rich stream".applied catalysis b-environmental 105.1-2(2011):103-110. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。