Hierarchically structured Fe/ZSM-5 as catalysts for the oxidation of benzene to phenol
文献类型：期刊论文
| 作者 | Koekkoek, Arjan J. J.1; Xin, Hongchuan2; Yang, Qihua2; Li, Can2; Hensen, Emiel J. M.1 |
| 刊名 | microporous and mesoporous materials
 |
| 出版日期 | 2011-11-01 |
| 卷号 | 145期号:1-3页码:172-181 |
| 关键词 | Hierarchical zeolite Fe/ZSM-5 Benzene oxidation Mesoporous Deactivation |
| 英文摘要 | different synthetic routes including carbon black and organosilane, templating and desilication were successfully employed to synthesize hierarchical fe/zsm-5 zeolites with improved catalytic performance in benzene oxidation to phenol with nitrous oxide. all these mesoporous zeolites show similar crystallinity, which is lower as compared to a conventional fe/zsm-5 catalyst. hierarchical fe/zsm-5 catalysts exhibit superior catalytic performance, especially in terms of stability, in the selective oxidation of benzene to phenol with nitrous oxide. the best performance is obtained for the organosilane templated zeolites. the high initial activity and stability are related to the high interconnectivity of the micropores and mesopores, thus limiting the zeolite domain size. this results in enhanced mass transport and prevents fast blocking of the micropore space by carbonaceous byproducts. (c) 2011 elsevier inc. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; nanoscience & nanotechnology ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; science & technology - other topics ; materials science |
| 关键词[WOS] | resonance raman-spectroscopy ; high-temperature treatment ; chemical-vapor-deposition ; selective oxidation ; mfi zeolites ; mesoporous materials ; nitrous-oxide ; zsm-5 zeolites ; iron ; hydroxylation |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000294974100026 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142706]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Koekkoek, Arjan J. J.,Xin, Hongchuan,Yang, Qihua,et al. Hierarchically structured Fe/ZSM-5 as catalysts for the oxidation of benzene to phenol[J]. microporous and mesoporous materials,2011,145(1-3):172-181. |
| APA | Koekkoek, Arjan J. J.,Xin, Hongchuan,Yang, Qihua,Li, Can,&Hensen, Emiel J. M..(2011).Hierarchically structured Fe/ZSM-5 as catalysts for the oxidation of benzene to phenol.microporous and mesoporous materials,145(1-3),172-181. |
| MLA | Koekkoek, Arjan J. J.,et al."Hierarchically structured Fe/ZSM-5 as catalysts for the oxidation of benzene to phenol".microporous and mesoporous materials 145.1-3(2011):172-181. |
入库方式： OAI收割
来源：大连化学物理研究所
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