The effects of Ti-based additives on the kinetics and reactions in LiH/MgB2 hydrogen storage system
文献类型：期刊论文
| 作者 | Zhang, Yao1; Morin, Francois2; Huot, Jacques2 |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2011-05-01 |
| 卷号 | 36期号:9页码:5425-5430 |
| 关键词 | Kinetics Reactions Hydrogen storage Ti-based additive LiH/MgB2 mixture |
| 英文摘要 | in this work we investigated the effect of ti, tih2, tib2, ticl3, and. tif3 additives on the hydrogen de/re-sorption kinetics and reaction pathways of lih/mgb2 mixture. from high pressure differential scanning calorimeter (hp-dsc) measurements it was found that these additives all effectively decrease the onset temperature of hydrogenation. the isothermal hydrogenation/dehydrogenation measurements suggest that ti, tih2, and tib2 can significantly improve the hydrogen sorption kinetics of lih/mgb2 mixture. the absorption kinetics of tif3 and ticl3 doped samples are slower than the baseline (2lih-mgb2 without additive), but their desorption kinetics are faster than the baseline and other additives doped systems. x-ray diffraction (xrd) analysis reveals that the additive ti in lih/mgb2 actively participates in both hydrogenation and dehydrogenation process, which can be regarded as an effective additive of this system. copyright (c) 2011, hydrogen energy publications, llc. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | libh4-mgh2 composite ; sorption kinetics ; mgh2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000290883100024 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142733]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Univ Quebec, Inst Rech Hydrogene, Trois Rivieres, PQ G9A 5H7, Canada |
| 推荐引用方式 GB/T 7714 | Zhang, Yao,Morin, Francois,Huot, Jacques. The effects of Ti-based additives on the kinetics and reactions in LiH/MgB2 hydrogen storage system[J]. international journal of hydrogen energy,2011,36(9):5425-5430. |
| APA | Zhang, Yao,Morin, Francois,&Huot, Jacques.(2011).The effects of Ti-based additives on the kinetics and reactions in LiH/MgB2 hydrogen storage system.international journal of hydrogen energy,36(9),5425-5430. |
| MLA | Zhang, Yao,et al."The effects of Ti-based additives on the kinetics and reactions in LiH/MgB2 hydrogen storage system".international journal of hydrogen energy 36.9(2011):5425-5430. |
入库方式： OAI收割
来源：大连化学物理研究所
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