Mechanismic Study of the Synthesis of Intrazeolite Pt Carbonyl Clusters
文献类型：期刊论文
| 作者 | Li Guangjin1; Guo Xiexian1; Toshiyuki, Fujimoto2; Masaru, Ichikawa2 |
| 刊名 | acta physico-chimica sinica
 |
| 出版日期 | 1994 |
| 卷号 | 10期号:8页码:710-715 |
| 关键词 | Zeolites Pt Carbonyl clusters (CO)-C-13 exchange EXAFS |
| 英文摘要 | the mechanism of the synthesis of platinum carbonyl clusters pt-3(co)(6)](n)(2-) (n=3, 4) in cages of nay was studied by ir, exafs (co)-c-13 exchange reaction and no interaction. the results suggest that oxidized pt species in nay cages reacts with co at 304-373k to form pto(co) (sigma(co)-2110cm(-1)) which aggregates into "pt-3(co)(6)" (sigma(co)-2112, 1896 and. 1841cm(-1)) and eventually converts into dark-green carbonyl cluster (pt-12(co)(24)](2-). the carbonyl "pt-3(co)(6)" can exchange with (co)-c-13 very quickly at 298k init the exchange reaction between (co)-c-13 and intrazeolite pt carbonyl clusters [pt-3(co)(0)](n)(2-) (n=3, 4) proceeds slowly even, at enhanced temperature such as 343k. it is interesting to find that no breaks successively the intra and inter-trigonal lit lit bonds of the pt-12 carbonyl clusters (even at 298 k) and the "pt-3(co)(6)" formed is further reacted to give pto(co) with the formation of n2o and co2 in the gas phase. pt-2(co)(24)](2-) can be reversibly regenerated from the pt subcarbonyls such as pto(co) and "pt-3(co)(6)" inside nay by reacting wich co at 300-353k. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000207589500008 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142740]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Hokkaido Univ, Catalysis Res Ctr, Sapporo, Hokkaido 060, Japan |
| 推荐引用方式 GB/T 7714 | Li Guangjin,Guo Xiexian,Toshiyuki, Fujimoto,et al. Mechanismic Study of the Synthesis of Intrazeolite Pt Carbonyl Clusters[J]. acta physico-chimica sinica,1994,10(8):710-715. |
| APA | Li Guangjin,Guo Xiexian,Toshiyuki, Fujimoto,&Masaru, Ichikawa.(1994).Mechanismic Study of the Synthesis of Intrazeolite Pt Carbonyl Clusters.acta physico-chimica sinica,10(8),710-715. |
| MLA | Li Guangjin,et al."Mechanismic Study of the Synthesis of Intrazeolite Pt Carbonyl Clusters".acta physico-chimica sinica 10.8(1994):710-715. |
入库方式： OAI收割
来源：大连化学物理研究所
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