A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd
文献类型:期刊论文
作者 | Xin Mei; Zhai Runsheng; Zhang Linhu; Guo Xiexian |
刊名 | acta physico-chimica sinica
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出版日期 | 1995 |
卷号 | 11期号:1页码:38-45 |
关键词 | Adsorption Desorption Exchange Kinetics |
英文摘要 | the kinetics of co desorption on pd(111) has been studied by using isotope switch method under the gas-phase pressures of single isotope and mixed ones. the experiments show that the desorption kinetics is non-linear and is first order plus second order on the saturated surface. based on the delocalized chemisorption model and gas-surface exchange mechanism, the analytic expressions for the desorption kinetics are derived and a dynamic reasoning of the non-linear kinetics has been described in detail. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000207590000008 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/142749] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | Acad Sinica, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
推荐引用方式 GB/T 7714 | Xin Mei,Zhai Runsheng,Zhang Linhu,et al. A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd[J]. acta physico-chimica sinica,1995,11(1):38-45. |
APA | Xin Mei,Zhai Runsheng,Zhang Linhu,&Guo Xiexian.(1995).A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd.acta physico-chimica sinica,11(1),38-45. |
MLA | Xin Mei,et al."A Study on the Nonlinear Kinetics of CO Desorption under the Gas Ambience on Pd".acta physico-chimica sinica 11.1(1995):38-45. |
入库方式: OAI收割
来源:大连化学物理研究所
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