THE PRODUCTION AND UV PHOTODISSOCIATION OF IRON-SULFUR BINARY CLUSTERS
文献类型:期刊论文
作者 | Yu Zhongde1; Feng Wanyang1; Zhang Nan1; Wu Xiaojun1; Gao Zhen1; Zhu Qihe1; Kong Fanao1; Zheng Lansun2; Huang Rongbin2 |
刊名 | acta physico-chimica sinica
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出版日期 | 1993 |
卷号 | 9期号:6页码:808-814 |
关键词 | Iron-surfur clusters UV-Photodissociation Laser vaporization Tandem time-of-flight mass spectrometer |
英文摘要 | the iron-sulfur cluster cluster ions; fensm+ (n = 1 - 13, m = 1 - 13), were produced by diredt laser vaporization of a solid sample containing a mixture of iron and sulfur powder. uv photodissociation of the cluster ons was studied with a tandem time-of-flight mass spectrometer. it was found that all the cluster ions with compositions of m = n, m = n - 1 or m = n + 5 have relatively larger abundances, indicating that they were more stable. the photodissociation results of fensm+ ions showed that when n approximate to m, the main channels were losses of neutral s atoms until n approximate to m, while for parent ions with n approximate to m, the main product ions have the m = n or m = n - 1 compositions. form these experimental results, it was proposed that the fensm+ ions might have structures similar to those of fensn cores in iron-sulfur protiens, while the structures of the fensm+(m > n) cluster ions could be considered to have a pattern of the fensm+ cores with some peripheral s atoms. |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | chemistry, physical |
研究领域[WOS] | chemistry |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000207577800016 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/142761] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing 100080, Peoples R China 2.Xiamen Univ, Dept Chem, Xiamen 361005, Peoples R China |
推荐引用方式 GB/T 7714 | Yu Zhongde,Feng Wanyang,Zhang Nan,et al. THE PRODUCTION AND UV PHOTODISSOCIATION OF IRON-SULFUR BINARY CLUSTERS[J]. acta physico-chimica sinica,1993,9(6):808-814. |
APA | Yu Zhongde.,Feng Wanyang.,Zhang Nan.,Wu Xiaojun.,Gao Zhen.,...&Huang Rongbin.(1993).THE PRODUCTION AND UV PHOTODISSOCIATION OF IRON-SULFUR BINARY CLUSTERS.acta physico-chimica sinica,9(6),808-814. |
MLA | Yu Zhongde,et al."THE PRODUCTION AND UV PHOTODISSOCIATION OF IRON-SULFUR BINARY CLUSTERS".acta physico-chimica sinica 9.6(1993):808-814. |
入库方式: OAI收割
来源:大连化学物理研究所
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