中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
The modification of molybdenum nitrides: the effect of the second metal component

文献类型:期刊论文

作者Li, Y; Zhang, Y; Raval, R; Li, C; Zhai, R; Xin, Q
刊名catalysis letters
出版日期1997
卷号48期号:3-4页码:239-245
关键词catalysis nitride HDN XRD SEM TDA coprecipitation molybdenum cobalt zirconium cerium bimetallic MoO3 gamma-Mo2N
英文摘要a set of mo2n-based bimetallic catalysts with high surface area around 140 m(2)/g have been successfully prepared from precursors obtained using the coprecipitation method. both the precursors and the end-catalysts were characterized using scanning electron microscopy (sem) and x-ray diffraction (xrd). the nitriding processes were monitored by differential thermal analysis (tda). the catalytic properties of co-mo bimetallic catalyst under medium pressure (3.0 mpa) are much better for the hydradenitrogenation of pyridine than those of pure gamma-mo2n and a commercially used sulfided como/al2o3 catalyst. the introduction of the second metal component has been shown to disrupt the morphology of the nitride phase with a greater concentration of (111) planes being present compared to (200) planes, a situation that is reversed compared to gamma-mo2n.
WOS标题词science & technology ; physical sciences
类目[WOS]chemistry, physical
研究领域[WOS]chemistry
关键词[WOS]reaction pathways ; surface oxygen ; carbides ; catalysts ; hydrodenitrogenation ; hydrodesulfurization ; hydrogenation ; tungsten ; mo2n ; area
收录类别SCI
语种英语
WOS记录号WOS:000071291600014
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/142812]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Liverpool, Leverhulme Ctr Innovat Catalysis, Liverpool L69 3BX, Merseyside, England
3.Univ Liverpool, Interdisciplinary Res Ctr Surface Sci, Liverpool L69 3BX, Merseyside, England
推荐引用方式
GB/T 7714
Li, Y,Zhang, Y,Raval, R,et al. The modification of molybdenum nitrides: the effect of the second metal component[J]. catalysis letters,1997,48(3-4):239-245.
APA Li, Y,Zhang, Y,Raval, R,Li, C,Zhai, R,&Xin, Q.(1997).The modification of molybdenum nitrides: the effect of the second metal component.catalysis letters,48(3-4),239-245.
MLA Li, Y,et al."The modification of molybdenum nitrides: the effect of the second metal component".catalysis letters 48.3-4(1997):239-245.

入库方式: OAI收割

来源:大连化学物理研究所

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