Study on the role of platinum in PtMo/Al2O3 for hydrodesulfurization of dibenzothiophene
文献类型：期刊论文
| 作者 | Wang, J; Li, WZ; Perot, G; Lemberton, JL; Yu, CY; Thomas, C; Zhang, YZ; Li, C; Xin, Q |
| 刊名 | spillover and migration of surface species on catalysts
 |
| 出版日期 | 1997 |
| 卷号 | 112页码:171-178 |
| 英文摘要 | hydrodesulfurization (hds) of dibenzothiophene (dbt) over ptmo/al2o3 was studied in the presence of h2s. pt was found to be an effective promoter for this reaction and the pt-containing catalyst was sulfur tolerance. data of the h-2-d-2 exchange revealed that both the amount of retained hydrogen and the initial rate of h-d exchange on the sulfided catalyst were increased by the introduction of a slight amount of pt into the catalyst, and corresponded very well to the catalytic activities for hds. the reduction and sulfidation of mo sites was also facilitated very much by pt, which was found by the results of the pulse reduction and sulfidation technique. it is proposed that, during the pretreatment of ptmo/al2o3, h-2 is first dissociated into hydrogen atoms on pt sites, which then spillover onto mo sites, providing a large amount of coordinately unsaturated mo sites for the hds reaction, and resulting in the higher hds activity than the unpromoted one. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | catalysts ; hydrodenitrogenation ; selectivity ; alumina |
| 收录类别 | ISTP ; SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000071952700018 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142817]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Poitiers, URA CNRS 350, Catalyse Chim Organ Lab, F-86022 Poitiers, France |
| 推荐引用方式 GB/T 7714 | Wang, J,Li, WZ,Perot, G,et al. Study on the role of platinum in PtMo/Al2O3 for hydrodesulfurization of dibenzothiophene[J]. spillover and migration of surface species on catalysts,1997,112:171-178. |
| APA | Wang, J.,Li, WZ.,Perot, G.,Lemberton, JL.,Yu, CY.,...&Xin, Q.(1997).Study on the role of platinum in PtMo/Al2O3 for hydrodesulfurization of dibenzothiophene.spillover and migration of surface species on catalysts,112,171-178. |
| MLA | Wang, J,et al."Study on the role of platinum in PtMo/Al2O3 for hydrodesulfurization of dibenzothiophene".spillover and migration of surface species on catalysts 112(1997):171-178. |
入库方式： OAI收割
来源：大连化学物理研究所
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