"Extracting" the Key Fragment in ETS-10 Crystallization and Its Application in AM-6 Assembly
文献类型：期刊论文
| 作者 | Guo, Meiling1,2; Feng, Zhaochi1; Li, Guanna1; Hofmann, Jan P.3; Pidko, Evgeny A.4; Magusin, Pieter C. M. M.4; Guo, Qiang1,2; Weckhuysen, Bert M.3; Hensen, Emiel J. M.4; Fan, Fengtao1 |
| 刊名 | chemistry-a european journal
 |
| 出版日期 | 2012-09-01 |
| 卷号 | 18期号:38页码:12078-12084 |
| 关键词 | crystallization hydrothermal synthesis Raman spectroscopy reaction mechanisms zeolites |
| 英文摘要 | the mechanism of crystallization of microporous titanosilicate ets-10 was investigated by raman spectroscopy combined with 29si magic-angle spinning (mas) nmr spectroscopy, dft calculations, and sem imaging. the formation of three-membered ring species is shown to be the key step in the hydrothermal synthesis of ets-10. they are formed by means of a complex process that involves the interaction of silicate species in the reaction mixture, which promotes the dissolution of tio2 particles. these insights into the mechanism of ets-10 growth led to the successful development of a new synthesis route to the vanadosilicate am-6 that involves the use of intermediates that contain three-membered ring species as an initiator. |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | microporous titanosilicate ets-10 ; autocatalytic nucleation ; vanadium substitution ; synthesis mechanism ; quantum wires ; mfi zeolite ; raman ; framework ; titanium ; units |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000308579100031 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142841]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China 3.Univ Utrecht, Debye Inst NanoMat Sci, NL-3584 CG Utrecht, Netherlands 4.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands |
| 推荐引用方式 GB/T 7714 | Guo, Meiling,Feng, Zhaochi,Li, Guanna,et al. "Extracting" the Key Fragment in ETS-10 Crystallization and Its Application in AM-6 Assembly[J]. chemistry-a european journal,2012,18(38):12078-12084. |
| APA | Guo, Meiling.,Feng, Zhaochi.,Li, Guanna.,Hofmann, Jan P..,Pidko, Evgeny A..,...&Li, Can.(2012)."Extracting" the Key Fragment in ETS-10 Crystallization and Its Application in AM-6 Assembly.chemistry-a european journal,18(38),12078-12084. |
| MLA | Guo, Meiling,et al.""Extracting" the Key Fragment in ETS-10 Crystallization and Its Application in AM-6 Assembly".chemistry-a european journal 18.38(2012):12078-12084. |
入库方式： OAI收割
来源：大连化学物理研究所
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