A high CO2 permselective mesoporous silica/carbon composite membrane for CO2 separation
文献类型：期刊论文
| 作者 | Li, Lin1; Wang, Tonghua1; Liu, Qingling1; Cao, Yiming2; Qiu, Jieshan1 |
| 刊名 | carbon
 |
| 出版日期 | 2012-11-01 |
| 卷号 | 50期号:14页码:5186-5195 |
| 英文摘要 | ordered mesoporous silica/carbon composite membranes with a high co2 permeability and selectivity were designed and prepared by incorporating sba-15 or mcm-48 particles into polymeric precursors followed by heat treatment. the as-made composite membranes were characterized by high-resolution transmission electron microscopy (hrtem), x-ray diffraction (xrd) and n-2 adsorption, of which the gas separation performance in terms of gas permeability and selectivity were evaluated using the single gas (co2, n-2, ch4) and gas mixtures (co2/n-2 and co2/ch4, 50/50 mol.%). in comparison to the pure carbon membranes and microporous zeolite/c composite membranes, the as-made mesoporous silica/c composite membranes, and the mcm-48/c composite membrane in particular, exhibit an outstanding co2 gas permeability and selectivity for the separation of co2/ch4 and co2/n-2 gas pairs owing to the smaller gas diffusive resistance through the membrane and additional gas permeation channels created by the incorporation of mesoporous silicas in carbon membrane matrix. the channel shape and dimension of mesoporous silicas are key parameters for governing the gas permeability of the as-made composite membranes. the gas separation mechanism and the functions of porous materials incorporated inside the composite membranes are addressed. (c) 2012 elsevier ltd. all rights reserved. |
| 类目[WOS] | chemistry, physical ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; materials science |
| 关键词[WOS] | molecular-sieve membranes ; nanoporous carbon membranes ; ether sulfone ketone) ; gas separation ; high-performance ; polymeric membranes ; silica ; transport ; purification ; fabrication |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000308898900023 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142844]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Univ Technol, Sch Chem Engn, Carbon Res Lab, State Key Lab Fine Chem, Dalian 116024, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Lin,Wang, Tonghua,Liu, Qingling,et al. A high CO2 permselective mesoporous silica/carbon composite membrane for CO2 separation[J]. carbon,2012,50(14):5186-5195. |
| APA | Li, Lin,Wang, Tonghua,Liu, Qingling,Cao, Yiming,&Qiu, Jieshan.(2012).A high CO2 permselective mesoporous silica/carbon composite membrane for CO2 separation.carbon,50(14),5186-5195. |
| MLA | Li, Lin,et al."A high CO2 permselective mesoporous silica/carbon composite membrane for CO2 separation".carbon 50.14(2012):5186-5195. |
入库方式： OAI收割
来源：大连化学物理研究所
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