Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols
文献类型：期刊论文
| 作者 | Xu, Weiliang2; Zhou, Yonggui1; Wang, Ruimin3; Wu, Guotao1; Chen, Ping1 |
| 刊名 | organic & biomolecular chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 10期号:2页码:367-371 |
| 英文摘要 | lithium amidoborane (linh2bh3, liab for short), is capable of chemoselectively reducing alpha,beta-unsaturated ketones to the corresponding allylic alcohols at ambient temperature. a mechanistic study shows that the reduction is via a double hydrogen transfer process. the protic h(n) and hydridic h(b) in amidoborane add to the o and c sites of the carbonyl group, respectively. |
| 类目[WOS] | chemistry, organic |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | asymmetric transfer hydrogenation ; ammonia-borane ; sodium-borohydride ; carbonyl-compounds ; mechanistic aspects ; metal amidoboranes ; conjugated ketones ; storage material ; aldehydes ; release |
| 收录类别 | SCI ; IC ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000298555700025 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142873]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Dalian Inst Chem Phys, Dalian, Peoples R China 2.Natl Univ Singapore, Singapore 117548, Singapore 3.Inner Mongolia Univ, Hohhot, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Weiliang,Zhou, Yonggui,Wang, Ruimin,et al. Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols[J]. organic & biomolecular chemistry,2012,10(2):367-371. |
| APA | Xu, Weiliang,Zhou, Yonggui,Wang, Ruimin,Wu, Guotao,&Chen, Ping.(2012).Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols.organic & biomolecular chemistry,10(2),367-371. |
| MLA | Xu, Weiliang,et al."Lithium amidoborane, a highly chemoselective reagent for the reduction of alpha,beta-unsaturated ketones to allylic alcohols".organic & biomolecular chemistry 10.2(2012):367-371. |
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来源：大连化学物理研究所
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