CO-PROX reactions on copper cerium oxide catalysts prepared by melt infiltration
文献类型：期刊论文
| 作者 | Li, Xiaobo1; Quek, Xian-Yang2; Ligthart, D. A. J. Michel2; Guo, Meiling1; Zhang, Yi2; Li, Can1; Yang, Qihua1; Hensen, Emiel J. M.2 |
| 刊名 | applied catalysis b-environmental
 |
| 出版日期 | 2012-07-23 |
| 卷号 | 123页码:424-432 |
| 关键词 | Copper Ceria Melt infiltration CO oxidation CO-PROX |
| 英文摘要 | a series of copper cerium oxide catalysts was prepared by melt infiltration routes using silica hollow spheres (shs) as the support material. their catalytic activity in co oxidation and preferential oxidation of co in h-2 stream (brox) strongly depend on the cu/ce ratio. lower ratios resulted in higher activity, indicating that finely dispersed cuo clusters that strongly interact with ceria are the active sites. the highest activity is found for an atomic cu/ce ratio of 1/8. the catalysts prepared by melt infiltration are more active than their counterparts prepared by conventional solution impregnation methods. the difference is attributed to the higher proportion of finely dispersed cuo clusters strongly interacting with ceria in the melt infiltrated catalysts. (c) 2012 elsevier b.v. all rights reserved. |
| 类目[WOS] | chemistry, physical ; engineering, environmental ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | cuo-ceo2 catalysts ; carbon-monoxide ; ceo2 catalysts ; structural characteristics ; composite catalysts ; cuo/ceo2 catalysts ; redox treatments ; solid-solutions ; total oxidation ; low-temperature |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000307159100047 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142934]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Eindhoven Univ Technol, Schuit Inst Catalysis, NL-5600 MB Eindhoven, Netherlands |
| 推荐引用方式 GB/T 7714 | Li, Xiaobo,Quek, Xian-Yang,Ligthart, D. A. J. Michel,et al. CO-PROX reactions on copper cerium oxide catalysts prepared by melt infiltration[J]. applied catalysis b-environmental,2012,123:424-432. |
| APA | Li, Xiaobo.,Quek, Xian-Yang.,Ligthart, D. A. J. Michel.,Guo, Meiling.,Zhang, Yi.,...&Hensen, Emiel J. M..(2012).CO-PROX reactions on copper cerium oxide catalysts prepared by melt infiltration.applied catalysis b-environmental,123,424-432. |
| MLA | Li, Xiaobo,et al."CO-PROX reactions on copper cerium oxide catalysts prepared by melt infiltration".applied catalysis b-environmental 123(2012):424-432. |
入库方式： OAI收割
来源：大连化学物理研究所
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