Local structure of titania decorated double-walled carbon nanotube characterized by scanning transmission X-ray microscopy
文献类型:期刊论文
作者 | Zhang, Hongbo1; Wang, Jian2; Pan, Xiulian1; Hu, Yongfeng2; Bao, Xinhe1 |
刊名 | journal of chemical physics |
出版日期 | 2012-05-07 |
卷号 | 136期号:17 |
英文摘要 | scanning transmission x-ray microscopy was demonstrated to deliver detailed local structure and chemical composition of a complicated system with titania nanoparticles dispersed inside and outside the double-walled carbon nanotube (dwnt) channels. areas with inhomogeneous distribution of titania and the associated water were particularly investigated at the c k-edge, ti l-edge, and o k-edge. the results show that titania nanoparticles located inside dwnts are present as amorphous, while those unsuccessfully introduced into the channels behave more like bulk materials in forms of anatase and rutile. strong interaction was detected between the confined titania and dwnts, as evidenced by up to 0.6 ev energy shift at the ti l-edge. strong hydration was observed for the as-prepared samples. functionalization due to reduction and oxidation between titania and carbon layer is observed upon heat-treatment. this detailed structural information of specific areas cannot be provided by other techniques such as hrtem, xrd, and xanes. (c) 2012 american institute of physics. [http://dx.doi.org/10.1063/1.4706515] |
WOS标题词 | science & technology ; physical sciences |
类目[WOS] | physics, atomic, molecular & chemical |
研究领域[WOS] | physics |
关键词[WOS] | resolution ; oxidation |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000303935700057 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/142949] |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Univ Saskatchewan, Canadian Light Source Inc, Saskatoon, SK S7N 0X4, Canada |
推荐引用方式 GB/T 7714 | Zhang, Hongbo,Wang, Jian,Pan, Xiulian,et al. Local structure of titania decorated double-walled carbon nanotube characterized by scanning transmission X-ray microscopy[J]. journal of chemical physics,2012,136(17). |
APA | Zhang, Hongbo,Wang, Jian,Pan, Xiulian,Hu, Yongfeng,&Bao, Xinhe.(2012).Local structure of titania decorated double-walled carbon nanotube characterized by scanning transmission X-ray microscopy.journal of chemical physics,136(17). |
MLA | Zhang, Hongbo,et al."Local structure of titania decorated double-walled carbon nanotube characterized by scanning transmission X-ray microscopy".journal of chemical physics 136.17(2012). |
入库方式: OAI收割
来源:大连化学物理研究所
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