Spinel ZnMn2O4 nanoplate assemblies fabricated via "escape-by-crafty-scheme" strategy
文献类型：期刊论文
| 作者 | Zhao, Jiao1,2; Wang, Fuqing2,3; Su, Panpan1,2; Li, Mingrun1; Chen, Jian3; Yang, Qihua1; Li, Can1 |
| 刊名 | journal of materials chemistry
 |
| 出版日期 | 2012 |
| 卷号 | 22期号:26页码:13328-13333 |
| 英文摘要 | a two-step process that differs in important details from previous methods used to prepare znmn2o4 nanoplate assemblies has been reported. this material was prepared by thermal transformation of metal-organic nanoparticles into metal-oxide nanoparticles based on the "escape-by-crafty-scheme" strategy. firstly, the nanoscale mixed-metal-organic frameworks (mmofs) precursor, znmn2-ptcda (ptcda = perylene-3,4,9,10-tetracarboxylic dianhydride), containing zn2+ and mn2+, was prepared by the designed soft chemical assembly of mixed metal ions and organic ligands at a molecular scale. in a second step, the mmofs are thermally transformed into spinel structured znmn2o4 with morphology inherited from the mmofs precursors. the well-crystallized spinel structure can be formed by thermal treatment of znmn2-ptcda at 350 degrees c, and is formed at temperatures >= 450 degrees c using the co-precipitation method. this "escape-by-crafty-scheme" strategy can be extended to the preparation of other spinel metal-oxide nanoparticles, e.g. comn2o4, and nimn2o4, with well-defined morphology inherited from the metal-organic precursors. the znmn2o4 nanoplate assemblies thermally treated at 450 degrees c have potential application in lithium ion batteries as anode materials, which show high specific capacity and good cyclability. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; materials science, multidisciplinary |
| 研究领域[WOS] | chemistry ; materials science |
| 关键词[WOS] | lithium-ion batteries ; coordination polymers ; storage material ; amorphous oxide ; anode material ; high-capacity ; li-storage ; electrodes ; transformation ; nanoparticles |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000305242300050 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142955]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Lab Adv Rechargeable Batteries, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhao, Jiao,Wang, Fuqing,Su, Panpan,et al. Spinel ZnMn2O4 nanoplate assemblies fabricated via "escape-by-crafty-scheme" strategy[J]. journal of materials chemistry,2012,22(26):13328-13333. |
| APA | Zhao, Jiao.,Wang, Fuqing.,Su, Panpan.,Li, Mingrun.,Chen, Jian.,...&Li, Can.(2012).Spinel ZnMn2O4 nanoplate assemblies fabricated via "escape-by-crafty-scheme" strategy.journal of materials chemistry,22(26),13328-13333. |
| MLA | Zhao, Jiao,et al."Spinel ZnMn2O4 nanoplate assemblies fabricated via "escape-by-crafty-scheme" strategy".journal of materials chemistry 22.26(2012):13328-13333. |
入库方式： OAI收割
来源：大连化学物理研究所
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