Structures of Al+(C2H4)(n) clusters: Mass-selected photodissociation and ab initio calculations
文献类型：期刊论文
| 作者 | Yuan, Jinyun; Zhao, Yuchao; Hou, Gaolei; Gao, Zhen; Zheng, Weijun |
| 刊名 | international journal of mass spectrometry
 |
| 出版日期 | 2012 |
| 卷号 | 309页码:49-55 |
| 关键词 | Mass spectrometry Mass-selection Photodissociation Aluminum-ethene |
| 英文摘要 | al+(c2h4)(n) clusters were produced by reaction of laser ablated al+ ions with ethene molecules seeded in a pulsed molecular beam, and detected with a reflectron time-of-flight mass spectrometer. the mass spectrum shows that an al+ ion can combine with at least eight ethene molecules to form al+(c2h4)(n) clusters. based on the photodissociation experiments and ab initio calculations, we suggest that an al+ ion can strongly interact with one or two c atoms to form al-c sigma-bonds and trigger addition reaction of ethene molecules to develop chain or ring structures. the interaction of al+ ion with ethene is different from the interaction between v+ ion and ethene molecules reported previously (int. j. mass. spectrom. 295 (2010)36), wherein a v+ ion can only combine with no more than four ethene molecules at similar experimental conditions and causes little change in the structures of the ethene molecules. (c) 2011 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | physics, atomic, molecular & chemical ; spectroscopy |
| 研究领域[WOS] | physics ; spectroscopy |
| 关键词[WOS] | electron-spin-resonance ; al-c2h4 complex ; atom-ethylene ; spectroscopy ; aluminum ; al+ ; dissociation ; ions ; solvation ; molecules |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000299063100007 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142976]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Inst Chem, State Key Lab Mol React Dynam, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yuan, Jinyun,Zhao, Yuchao,Hou, Gaolei,et al. Structures of Al+(C2H4)(n) clusters: Mass-selected photodissociation and ab initio calculations[J]. international journal of mass spectrometry,2012,309:49-55. |
| APA | Yuan, Jinyun,Zhao, Yuchao,Hou, Gaolei,Gao, Zhen,&Zheng, Weijun.(2012).Structures of Al+(C2H4)(n) clusters: Mass-selected photodissociation and ab initio calculations.international journal of mass spectrometry,309,49-55. |
| MLA | Yuan, Jinyun,et al."Structures of Al+(C2H4)(n) clusters: Mass-selected photodissociation and ab initio calculations".international journal of mass spectrometry 309(2012):49-55. |
入库方式： OAI收割
来源：大连化学物理研究所
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