Morphology-dependent nanocatalysis on metal oxides
文献类型：期刊论文
| 作者 | Li Yong; Shen WenJie |
| 刊名 | science china-chemistry
 |
| 出版日期 | 2012-12-01 |
| 卷号 | 55期号:12页码:2485-2496 |
| 关键词 | nanocatalysis morphology-dependence metal oxides structure-reactivity relationship catalyst preparation |
| 英文摘要 | the design and fabrication of solid nanomaterials are the key issues in heterogeneous catalysis to achieve desired performance. traditionally, the main theme is to reduce the size of the catalyst particles as small as possible for maximizing the number of active sites. in recent years, the rapid advancement in materials science has enabled us to fabricate catalyst particles with tunable morphology. consequently, both size modulation and morphology control of the catalyst particles can be achieved independently or synergistically to optimize their catalytic properties. in particular, morphology control of solid catalyst particles at the nanometer level can selectively expose the reactive crystal facets, and thus drastically promote their catalytic performance. in this review, we summarize our recent work on the morphology impact of co3o4, ceo2 and fe2o3 nanomaterials in catalytic reactions, together with related literature on morphology-dependent nanocatalysis of metal oxides, to demonstrate the importance of tuning the shape of oxide-nanocatalysts for prompting their activity, selectivity and stability, which is a rapidly growing topic in heterogeneous catalysis. the fundamental understanding of the active sites in morphology-tunable oxides that are enclosed by reactive crystal facets is expected to direct the development of highly efficient nanocatalysts. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | low-temperature oxidation ; shape-controlled synthesis ; aqueous-phase synthesis ; gas-sensing properties ; catalytic-activity ; carbon-monoxide ; co oxidation ; iron-oxide ; heterogeneous catalysis ; platinum nanocrystals |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000312531300002 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/142998]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li Yong,Shen WenJie. Morphology-dependent nanocatalysis on metal oxides[J]. science china-chemistry,2012,55(12):2485-2496. |
| APA | Li Yong,&Shen WenJie.(2012).Morphology-dependent nanocatalysis on metal oxides.science china-chemistry,55(12),2485-2496. |
| MLA | Li Yong,et al."Morphology-dependent nanocatalysis on metal oxides".science china-chemistry 55.12(2012):2485-2496. |
入库方式： OAI收割
来源：大连化学物理研究所
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