Hydrolysis reaction of ball-milled Mg-metal chlorides composite for hydrogen generation for fuel cells
文献类型：期刊论文
| 作者 | Wang, Shuang1,3; Sun, Li-Xian1,4; Xu, Fen2; Jiao, Cheng-Li1,3; Zhang, Jian1; Zhou, Huai-Ying4; Huang, Feng-Lei5 |
| 刊名 | international journal of hydrogen energy
 |
| 出版日期 | 2012-04-01 |
| 卷号 | 37期号:8页码:6771-6775 |
| 关键词 | Hydrogen generation Mg-based-material Ball milling Hydrolysis reaction Kinetics |
| 英文摘要 | in this paper, the hydrolysis properties for hydrogen generation by mg-metal chlorides composites in pure water are investigated. the composites were prepared by high energy ball milling. it is found that the mg-metal chlorides composites are very promising for hydrogen generation by hydrolysis reaction. the micro-galvanic cell formed by mg and the other metal which produced by replacement reaction occurred during the ball-milling process is very effective for improving the hydrolysis reactivity. based on the investigations of different kinds of chlorides additives, it is found that the mg-10 wt% fecl3 composite ball-milled for 30 min has the best hydrolysis properties with an initial hydrogen generation rate of 1479.1 ml*g(-1) min(-1) and a theoretical hydrogen production yield of 98% in 2 min. copyright (c) 2012, hydrogen energy publications, llc. published by elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, physical ; electrochemistry ; energy & fuels |
| 研究领域[WOS] | chemistry ; electrochemistry ; energy & fuels |
| 关键词[WOS] | chemical hydrides ; magnesium ; water |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000303952300047 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143026]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 2.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China 3.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 4.Guilin Univ Elect Technol, Dept Mat Sci & Engn, Guilin 541004, Peoples R China 5.Beijing Inst Technol, State Key Lab Explos Sci & Technol, Beijing 100081, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Shuang,Sun, Li-Xian,Xu, Fen,et al. Hydrolysis reaction of ball-milled Mg-metal chlorides composite for hydrogen generation for fuel cells[J]. international journal of hydrogen energy,2012,37(8):6771-6775. |
| APA | Wang, Shuang.,Sun, Li-Xian.,Xu, Fen.,Jiao, Cheng-Li.,Zhang, Jian.,...&Huang, Feng-Lei.(2012).Hydrolysis reaction of ball-milled Mg-metal chlorides composite for hydrogen generation for fuel cells.international journal of hydrogen energy,37(8),6771-6775. |
| MLA | Wang, Shuang,et al."Hydrolysis reaction of ball-milled Mg-metal chlorides composite for hydrogen generation for fuel cells".international journal of hydrogen energy 37.8(2012):6771-6775. |
入库方式： OAI收割
来源：大连化学物理研究所
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