Lattice potential energies and thermochemical properties of triethylammonium halides (Et3NHX) (X = Cl, Br, and I)
文献类型：期刊论文
| 作者 | Liu, Yu-Pu1; Tan, Zhi-Cheng2,3; Di, You-Ying1; Xing, Yi-Ting1; Zhang, Peng1 |
| 刊名 | journal of chemical thermodynamics
 |
| 出版日期 | 2012-02-01 |
| 卷号 | 45期号:1页码:100-108 |
| 关键词 | Triethylammonium halides X-ray diffraction Lattice potential energy Molar enthalpies of dissolution at infinite dilution Hydration enthalpy |
| 英文摘要 | a series of triethylammonium halides (et3nhcl, et3nhbr, and et(3)nh1) was synthesized. the crystal structures of the three compounds were characterized by x-ray crystallography. the lattice potential energies and ionic radius of the common cation of the three compounds were obtained from crystallographic data. molar enthalpies of dissolution of the compounds at various values of molality were measured in the double-distilled water at t = 298.150 k by means of an isoperibol solution-reaction calorimeter. according to pitzer's theory, the values of molar enthalpies of dissolution at infinite dilution and pitzer's parameters of the compounds were obtained. the values of apparent relative molar enthalpies, relative partial molar enthalpies of the solvent and the compounds at different molalities were derived from the experimental values of molar enthalpies of dissolution of the compounds. finally, hydration enthalpy of the common cation et3nh+ was calculated to be delta h+ = (150.386 +/- 4.071) kj . mol(-1) by designing a thermochemical cycle. (c) 2011 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | thermodynamics ; chemistry, physical |
| 研究领域[WOS] | thermodynamics ; chemistry |
| 关键词[WOS] | low-temperature ; crystal-structure ; enthalpy ; thermodynamics ; redetermination ; chloride ; volumes |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000297830800014 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143033]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaocheng Univ, Coll Chem & Chem Engn, Liaocheng 252059, Shandong, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, China Ionic Liquid Lab, Dalian 116023, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Thermochem Lab, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Yu-Pu,Tan, Zhi-Cheng,Di, You-Ying,et al. Lattice potential energies and thermochemical properties of triethylammonium halides (Et3NHX) (X = Cl, Br, and I)[J]. journal of chemical thermodynamics,2012,45(1):100-108. |
| APA | Liu, Yu-Pu,Tan, Zhi-Cheng,Di, You-Ying,Xing, Yi-Ting,&Zhang, Peng.(2012).Lattice potential energies and thermochemical properties of triethylammonium halides (Et3NHX) (X = Cl, Br, and I).journal of chemical thermodynamics,45(1),100-108. |
| MLA | Liu, Yu-Pu,et al."Lattice potential energies and thermochemical properties of triethylammonium halides (Et3NHX) (X = Cl, Br, and I)".journal of chemical thermodynamics 45.1(2012):100-108. |
入库方式： OAI收割
来源：大连化学物理研究所
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