Synergistic Catalysis of Fe2O3 and TiF3 Additives on the LiBH4-MgH2 Composite
文献类型：期刊论文
| 作者 | Zhang Hui1,2; Zhou Yi-Xi1,2; Sun Li-Xian1; Cao Zhong2; Xu Fen3; Liu Shu-Sheng1; Zhang Jian1; Song Li-Fang1; Si Xiao-Liang1; Jiao Cheng-Li1 |
| 刊名 | chemical journal of chinese universities-chinese
 |
| 出版日期 | 2012-04-10 |
| 卷号 | 33期号:4页码:781-785 |
| 关键词 | LiBH4 MgH2 Fe2O3 TiF3 Synergistic catalysis |
| 英文摘要 | five systems (2libh(4)-mgh2, 2libh(4)-mgh2-10% fe2o3, 2libh(4)-mgh2-10% tif3, 2libh(4)-mgh2-5% fe2o3-5% tif3 and 2libh(4)-mgh2-10% fe2o3-10% tif3) were prepared by hall milling. they were investigated through thermogravimeteric analysis (tg), diffraction scanning calorimetric (dsc), powder x-ray diffraction (xrd), fourier transformed infrared spectrometer (ftir) and pressure-content-temperature (pct). the addition of fe2o3 and tif3 improved the hydrogen release property of the libh4-mgh2 complex system effectively. especially, the codoped system (2libh(4)-mgh2-10% fe2o3-10% tif3) starts to release hydrogen at around 110 degrees c and can release as much as 9.6%. besides, the results of pct show that the codoped system (2libh(4)-mgh2-5% fe2o3-5% tif3) can release about 8.6% hydrogen within 10 min at 400 degrees c. the properties of the codoped system are better than the other two single doped systems, which partly incarnated the synergistic catalysis of fe2o3 and tif3. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | reversible hydrogen storage ; naalh4 ; lialh4 ; carbon |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000303691300024 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143040]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China 3.Liaoning Normal Univ, Chem & Chem Engn Sch, Dalian 116029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang Hui,Zhou Yi-Xi,Sun Li-Xian,et al. Synergistic Catalysis of Fe2O3 and TiF3 Additives on the LiBH4-MgH2 Composite[J]. chemical journal of chinese universities-chinese,2012,33(4):781-785. |
| APA | Zhang Hui.,Zhou Yi-Xi.,Sun Li-Xian.,Cao Zhong.,Xu Fen.,...&Li Fen.(2012).Synergistic Catalysis of Fe2O3 and TiF3 Additives on the LiBH4-MgH2 Composite.chemical journal of chinese universities-chinese,33(4),781-785. |
| MLA | Zhang Hui,et al."Synergistic Catalysis of Fe2O3 and TiF3 Additives on the LiBH4-MgH2 Composite".chemical journal of chinese universities-chinese 33.4(2012):781-785. |
入库方式： OAI收割
来源：大连化学物理研究所
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