Carbon paper coated with supported tungsten trioxide as novel electrode for all-vanadium flow battery
文献类型：期刊论文
| 作者 | Yao, Chuan1,2; Zhang, Huamin1; Liu, Tao1; Li, Xianfeng1; Liu, Zonghao3 |
| 刊名 | journal of power sources
 |
| 出版日期 | 2012-11-15 |
| 卷号 | 218页码:455-461 |
| 关键词 | Vanadium redox flow battery Tungsten trioxide/super activated carbon Carbon paper Electrochemical performance Voltage efficiency |
| 英文摘要 | a novel carbon paper electrode coated with supported tungsten trioxide is developed to improve the carbon fiber's electrochemical performance toward the vanadium redox couples. super activated carbon supported tungsten trioxide (wo3/sac) is prepared via an impregnation method and characterized by x-ray diffraction and scanning electron microscopy. the electrochemical performance of the prepared electrode is evaluated with cyclic voltammetry and electrochemical impedance spectroscopy. results show that wo3/sac exhibits excellent electro-catalytic activity and kinetic reversibility toward the vanadium redox couples. by adding the wo3/sac, the charge transfer resistances for both the positive and the negative reactions are significantly reduced. using as prepared electrodes, the columbic efficiency (ce), voltage efficiency (ve) and energy efficiency (ee) of the vanadium redox flow battery at 50 ma cm(-2) are 94.5%, 85.2% and 80.5%, respectively, which are much higher than that of the cell assembled with pristine carbon paper electrodes. (c) 2012 elsevier b.v. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | electrochemistry ; energy & fuels |
| 研究领域[WOS] | electrochemistry ; energy & fuels |
| 关键词[WOS] | chemical modification ; positive electrode ; redox reactions ; graphite felt ; performance ; systems ; cell |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000309038100062 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143051]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100039, Peoples R China 3.Dalian Rongke Power Co Ltd, Dalian 116025, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yao, Chuan,Zhang, Huamin,Liu, Tao,et al. Carbon paper coated with supported tungsten trioxide as novel electrode for all-vanadium flow battery[J]. journal of power sources,2012,218:455-461. |
| APA | Yao, Chuan,Zhang, Huamin,Liu, Tao,Li, Xianfeng,&Liu, Zonghao.(2012).Carbon paper coated with supported tungsten trioxide as novel electrode for all-vanadium flow battery.journal of power sources,218,455-461. |
| MLA | Yao, Chuan,et al."Carbon paper coated with supported tungsten trioxide as novel electrode for all-vanadium flow battery".journal of power sources 218(2012):455-461. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。