Immobilization of Cinchona Quaternary Ammonium Salts as the Chiral Phase Transfer Catalysts on Multi-walled Carbon Nanotubes and Their Application in Enantioselective Alkylation
文献类型：期刊论文
| 作者 | Liu Jian1; Liu Yan2; Shi Xin1; Yang Qihua2 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2012-05-01 |
| 卷号 | 33期号:5页码:891-897 |
| 关键词 | multi-walled carbon nanotube chiral phase transfer catalyst cinchona alkaloid adsorption enantioselective alkylation |
| 英文摘要 | the pyrene-tagged cinchona quaternary ammonium salt, the chiral phase transfer catalysts (ptc-1), was synthesized and immobilized on multi-walled carbon nanotubes (mwcnts). the new catalysts (ptc-1/mwcnts) were employed in enantioselective alkylation of n-(diphenylmethyene)glycine tert-butyl ester. uv-vis absorption spectra show the effect of different organic solvents on the adsorption and desorption of ptc-1 onto and from mwcnts, respectively. the results show that 5.3 mg ptc-1 can be loaded on 10 mg mwcnts in toluene, and 0.02025 mg ptc-1 was desorbed from 12.7 mg ptc-1/mwcnts when washed by chcl3. in the enantioselective alkylation of different halohydrocarbons with n-(diphenylmethyene)glycine tert-butyl ester using ptc-1/mwcnts as a catalyst, the alkylating products were obtained with high yield and ee value. furthermore, ptc-1/mwcnts catalyst can be recovered and used repeatedly. ptc-1/mwcnts as a new catalyst is effective in enantioselective alkylation of multiple halohydrocarbon. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | supported nickel-catalysts ; electrooxidation ; performance |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000304019200022 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143098]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Liaoning Normal Univ, Sch Chem & Chem Engn, Inst Chem Functionalized Mat, Dalian 116029, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu Jian,Liu Yan,Shi Xin,et al. Immobilization of Cinchona Quaternary Ammonium Salts as the Chiral Phase Transfer Catalysts on Multi-walled Carbon Nanotubes and Their Application in Enantioselective Alkylation[J]. chinese journal of catalysis,2012,33(5):891-897. |
| APA | Liu Jian,Liu Yan,Shi Xin,&Yang Qihua.(2012).Immobilization of Cinchona Quaternary Ammonium Salts as the Chiral Phase Transfer Catalysts on Multi-walled Carbon Nanotubes and Their Application in Enantioselective Alkylation.chinese journal of catalysis,33(5),891-897. |
| MLA | Liu Jian,et al."Immobilization of Cinchona Quaternary Ammonium Salts as the Chiral Phase Transfer Catalysts on Multi-walled Carbon Nanotubes and Their Application in Enantioselective Alkylation".chinese journal of catalysis 33.5(2012):891-897. |
入库方式： OAI收割
来源：大连化学物理研究所
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