Effect of Precipitation Temperature on the Performance of CuO/ZnO/CeO2/ZrO2 Catalyst for Methanol Steam Reforming
文献类型:期刊论文
作者 | Zhang Lei1,2; Pan Liwei1; Ni Changjun1; Sun Tianjun1; Zhao Shengsheng1; Wang Shudong1; Hu Yongkang3; Wang Anjie2 |
刊名 | chinese journal of catalysis
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出版日期 | 2012-12-01 |
卷号 | 33期号:12页码:1958-1964 |
关键词 | hydrogen methanol steam reforming precipitation temperature copper oxide zinc oxide cerium oxide zirconium oxide |
英文摘要 | a series of cuo/zno/ceo2/zro2 catalyst samples for methanol steam reforming were prepared by a co-precipitation procedure, and the effect of precipitation temperature on the catalytic performance was investigated. all the samples were characterized by n-2 adsorption, x-ray diffraction, temperature-programmed reduction, and n2o titration. it is shown that the precipitation temperature remarkably influenced the catalyst structure and property. when the precipitation temperature was 60 degrees c, the catalyst exhibited the best activity with suppressed co formation. compared with commercial catalyst (cb-7), the cezr as support instead of the al2o3 can dramatically improve the conversion at low temperature, effectively inhibit the co generation, reduce the subsequent co removing process, which was helpful for methanol stream reforming technology using in the proton exchange membrane fuel cell applications. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | zinc-oxide catalysts ; fuel-cell ; cuo/zno/al2o3 catalyst ; monolithic catalyst ; hydrogen-production ; alumina catalysts ; optimization ; spectroscopy ; precursor ; oxidation |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000313139200013 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/143106] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China 3.Fushun Res Inst Petr & Petrochem, Fushun 113001, Liaoning, Peoples R China |
推荐引用方式 GB/T 7714 | Zhang Lei,Pan Liwei,Ni Changjun,et al. Effect of Precipitation Temperature on the Performance of CuO/ZnO/CeO2/ZrO2 Catalyst for Methanol Steam Reforming[J]. chinese journal of catalysis,2012,33(12):1958-1964. |
APA | Zhang Lei.,Pan Liwei.,Ni Changjun.,Sun Tianjun.,Zhao Shengsheng.,...&Wang Anjie.(2012).Effect of Precipitation Temperature on the Performance of CuO/ZnO/CeO2/ZrO2 Catalyst for Methanol Steam Reforming.chinese journal of catalysis,33(12),1958-1964. |
MLA | Zhang Lei,et al."Effect of Precipitation Temperature on the Performance of CuO/ZnO/CeO2/ZrO2 Catalyst for Methanol Steam Reforming".chinese journal of catalysis 33.12(2012):1958-1964. |
入库方式: OAI收割
来源:大连化学物理研究所
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