中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of Precipitation Temperature on the Performance of CuO/ZnO/CeO2/ZrO2 Catalyst for Methanol Steam Reforming

文献类型:期刊论文

作者Zhang Lei1,2; Pan Liwei1; Ni Changjun1; Sun Tianjun1; Zhao Shengsheng1; Wang Shudong1; Hu Yongkang3; Wang Anjie2
刊名chinese journal of catalysis
出版日期2012-12-01
卷号33期号:12页码:1958-1964
关键词hydrogen methanol steam reforming precipitation temperature copper oxide zinc oxide cerium oxide zirconium oxide
英文摘要a series of cuo/zno/ceo2/zro2 catalyst samples for methanol steam reforming were prepared by a co-precipitation procedure, and the effect of precipitation temperature on the catalytic performance was investigated. all the samples were characterized by n-2 adsorption, x-ray diffraction, temperature-programmed reduction, and n2o titration. it is shown that the precipitation temperature remarkably influenced the catalyst structure and property. when the precipitation temperature was 60 degrees c, the catalyst exhibited the best activity with suppressed co formation. compared with commercial catalyst (cb-7), the cezr as support instead of the al2o3 can dramatically improve the conversion at low temperature, effectively inhibit the co generation, reduce the subsequent co removing process, which was helpful for methanol stream reforming technology using in the proton exchange membrane fuel cell applications.
WOS标题词science & technology ; physical sciences ; technology
类目[WOS]chemistry, applied ; chemistry, physical ; engineering, chemical
研究领域[WOS]chemistry ; engineering
关键词[WOS]zinc-oxide catalysts ; fuel-cell ; cuo/zno/al2o3 catalyst ; monolithic catalyst ; hydrogen-production ; alumina catalysts ; optimization ; spectroscopy ; precursor ; oxidation
收录类别SCI
语种英语
WOS记录号WOS:000313139200013
公开日期2015-11-17
源URL[http://159.226.238.44/handle/321008/143106]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Dalian Univ Technol, State Key Lab Fine Chem, Dalian 116024, Liaoning, Peoples R China
3.Fushun Res Inst Petr & Petrochem, Fushun 113001, Liaoning, Peoples R China
推荐引用方式
GB/T 7714
Zhang Lei,Pan Liwei,Ni Changjun,et al. Effect of Precipitation Temperature on the Performance of CuO/ZnO/CeO2/ZrO2 Catalyst for Methanol Steam Reforming[J]. chinese journal of catalysis,2012,33(12):1958-1964.
APA Zhang Lei.,Pan Liwei.,Ni Changjun.,Sun Tianjun.,Zhao Shengsheng.,...&Wang Anjie.(2012).Effect of Precipitation Temperature on the Performance of CuO/ZnO/CeO2/ZrO2 Catalyst for Methanol Steam Reforming.chinese journal of catalysis,33(12),1958-1964.
MLA Zhang Lei,et al."Effect of Precipitation Temperature on the Performance of CuO/ZnO/CeO2/ZrO2 Catalyst for Methanol Steam Reforming".chinese journal of catalysis 33.12(2012):1958-1964.

入库方式: OAI收割

来源:大连化学物理研究所

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