State-to-state differential cross-sections for the reactive scattering of H*(n) with o-D-2
文献类型：期刊论文
| 作者 | Yu, Shengrui; Yuan, Kaijun; Song, Hui; Xu, Xin; Dai, Dongxu; Zhang, Dong H.; Yang, Xueming |
| 刊名 | chemical science
 |
| 出版日期 | 2012 |
| 卷号 | 3期号:9页码:2839-2842 |
| 英文摘要 | full quantum-state resolved differential cross-sections of the h*(n) + o-d-2 -> hd + d*(n') reaction have been measured for the first time using the rydberg h-atom time-of-flight method. experimental results show that the angular distributions of hd product rotational states show a strong preference for forward scattering. this result is considerably different to that predicted by full quantum mechanical calculations on the corresponding ion-molecule reaction, suggesting that the ionic core and rydberg electron coupling cannot be neglected in the rydberg h-atom reactive scattering with d-2 and, therefore, that the fermi independent-collider model is not valid in describing the dynamics of rydberg atom reactions with molecules. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | potential-energy surfaces ; h-3(+) ; dynamics ; hydrogen ; atoms ; collisions ; system |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000306931300024 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143124]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yu, Shengrui,Yuan, Kaijun,Song, Hui,et al. State-to-state differential cross-sections for the reactive scattering of H*(n) with o-D-2[J]. chemical science,2012,3(9):2839-2842. |
| APA | Yu, Shengrui.,Yuan, Kaijun.,Song, Hui.,Xu, Xin.,Dai, Dongxu.,...&Yang, Xueming.(2012).State-to-state differential cross-sections for the reactive scattering of H*(n) with o-D-2.chemical science,3(9),2839-2842. |
| MLA | Yu, Shengrui,et al."State-to-state differential cross-sections for the reactive scattering of H*(n) with o-D-2".chemical science 3.9(2012):2839-2842. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。