In-Situ FT-IR Study on Methane Combustion over Pd/NiAl2O4 Catalyst
文献类型:期刊论文
作者 | Liu Ying1,2; Wang Sheng1; Gao Diannan1; Pan Qiushi1,2; Wang Shudong1 |
刊名 | chinese journal of catalysis
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出版日期 | 2012-09-01 |
卷号 | 33期号:9页码:1552-1557 |
关键词 | palladium nickel aluminum spinel methane catalytic combustion in-situ infrared spectroscopy |
英文摘要 | the mechanism of methane combustion on pd/nial2o4 catalyst was studied by in-situ ft-ir spectroscopy. the results showed that the transformation from formate to carbonate was the rate-determining step for the reaction. after reaction under lean fuel condition, the active site of pre-reduced catalyst was still pd-pdo mixed phase. the existence of metal pd would convert o-2 to o-2(-) species, which would facilitate the transformation from formate to carbonate. |
WOS标题词 | science & technology ; physical sciences ; technology |
类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
研究领域[WOS] | chemistry ; engineering |
关键词[WOS] | low-temperature ; oxidation ; palladium ; pd/al2o3 ; spectroscopy ; stability ; behavior ; surface ; water ; drift |
收录类别 | SCI |
语种 | 英语 |
WOS记录号 | WOS:000308972700017 |
公开日期 | 2015-11-17 |
源URL | [http://159.226.238.44/handle/321008/143131] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
推荐引用方式 GB/T 7714 | Liu Ying,Wang Sheng,Gao Diannan,et al. In-Situ FT-IR Study on Methane Combustion over Pd/NiAl2O4 Catalyst[J]. chinese journal of catalysis,2012,33(9):1552-1557. |
APA | Liu Ying,Wang Sheng,Gao Diannan,Pan Qiushi,&Wang Shudong.(2012).In-Situ FT-IR Study on Methane Combustion over Pd/NiAl2O4 Catalyst.chinese journal of catalysis,33(9),1552-1557. |
MLA | Liu Ying,et al."In-Situ FT-IR Study on Methane Combustion over Pd/NiAl2O4 Catalyst".chinese journal of catalysis 33.9(2012):1552-1557. |
入库方式: OAI收割
来源:大连化学物理研究所
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