Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts
文献类型：期刊论文
| 作者 | Song Xiangen1,3; Ding Yunjie1,2; Chen Weimiao1; Dong Wenda1,3; Pei Yanpeng1,3; Zang Juan1,3; Yan Li1; Lu Yuan1 |
| 刊名 | chinese journal of catalysis
 |
| 出版日期 | 2012-12-01 |
| 卷号 | 33期号:12页码:1938-1944 |
| 关键词 | carbon monoxide hydrogenation oxygenates metal phosphides silica iron phosphide nickel phosphide |
| 英文摘要 | a series of silica supported iron and nickel metal phosphides with different molar ratios of p to metal were synthesized by the temperature programmed reduction method. their catalytic performance for co hydrogenation in a fixed bed reactor was tested with the conditions of 553 k, 5.0 mpa, and h-2:co = 2 (molar ratio). with the fepx/sio2 catalysts (x denotes the molar ratio of p to metal), the product was a mixture of oxygenates containing methanol as the major component. with the nipx/sio2 samples, the liquid product was mainly methanol. the fe2p, fe3p, ni, ni2p, ni3p, and ni12p5 phases were stable during co hydrogenation, while most of the metallic fe phase transformed into iron carbide. |
| WOS标题词 | science & technology ; physical sciences ; technology |
| 类目[WOS] | chemistry, applied ; chemistry, physical ; engineering, chemical |
| 研究领域[WOS] | chemistry ; engineering |
| 关键词[WOS] | synthesis gas conversion ; high-temperature ; rh catalysts ; syngas ; ethanol ; hydrodesulfurization ; ammoxidation ; reduction ; ni2p/sio2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000313139200010 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143133]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 3.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Song Xiangen,Ding Yunjie,Chen Weimiao,et al. Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts[J]. chinese journal of catalysis,2012,33(12):1938-1944. |
| APA | Song Xiangen.,Ding Yunjie.,Chen Weimiao.,Dong Wenda.,Pei Yanpeng.,...&Lu Yuan.(2012).Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts.chinese journal of catalysis,33(12),1938-1944. |
| MLA | Song Xiangen,et al."Synthesis of Mixed Alcohols from CO Hydrogenation over Iron and Nickel Metal Phosphide Catalysts".chinese journal of catalysis 33.12(2012):1938-1944. |
入库方式： OAI收割
来源：大连化学物理研究所
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