O-2((1)Delta) Yield Measurement by Raman Spectroscopy With Elimination Chlorine Fluorescence Interference
文献类型：期刊论文
| 作者 | Cui, Rong-rong; Shi, Wen-bo; Deng, Lie-zheng; Yang, He-ping; Sha, Guo-he; Zhang, Cun-hao |
| 刊名 | chinese journal of chemical physics
 |
| 出版日期 | 2012-04-01 |
| 卷号 | 25期号:2页码:142-146 |
| 关键词 | Chemical oxygen iodine laser Singlet oxygen yield Spontaneous Raman spectroscopy Chlorine fluorescence |
| 英文摘要 | deleterious chlorine fluorescence was found to occur at the same frequency as the raman scattering of o-2((1)delta) and o-2((3)sigma), seriously affecting the o-2((1)delta) yield measurement in the reaction of chlorine with basic hydrogen peroxide by use of the raman spectroscopy technique. to solve this problem we have taken advantage of the fact that raman radiation is always strongly polarized while fluorescence is essentially non-polarized in a gaseous medium. when chlorine utilization of a singlet oxygen generator is 88%, o-2((1)delta) yield reaches (42.4 +/- 7.4)% with the effect of chlorine fluorescence completely eliminated. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | physics, atomic, molecular & chemical |
| 研究领域[WOS] | physics |
| 关键词[WOS] | singlet oxygen generator ; hydrogen-peroxide ; iodine lasers ; mechanisms ; h2o2 |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000304381000004 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143140]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cui, Rong-rong,Shi, Wen-bo,Deng, Lie-zheng,et al. O-2((1)Delta) Yield Measurement by Raman Spectroscopy With Elimination Chlorine Fluorescence Interference[J]. chinese journal of chemical physics,2012,25(2):142-146. |
| APA | Cui, Rong-rong,Shi, Wen-bo,Deng, Lie-zheng,Yang, He-ping,Sha, Guo-he,&Zhang, Cun-hao.(2012).O-2((1)Delta) Yield Measurement by Raman Spectroscopy With Elimination Chlorine Fluorescence Interference.chinese journal of chemical physics,25(2),142-146. |
| MLA | Cui, Rong-rong,et al."O-2((1)Delta) Yield Measurement by Raman Spectroscopy With Elimination Chlorine Fluorescence Interference".chinese journal of chemical physics 25.2(2012):142-146. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。