The acid free asymmetric intermolecular alpha-alkylation of aldehydes in fluorinated alcohols
文献类型：期刊论文
| 作者 | Xiao, Jian1,2; Zhao, Kai1; Loh, Teck-Peng1 |
| 刊名 | chemical communications
 |
| 出版日期 | 2012 |
| 卷号 | 48期号:29页码:3548-3550 |
| 英文摘要 | the acid free asymmetric intermolecular alpha-alkylation of aldehydes with alcohols has been discovered using trifluoroethanol as solvent. this unprecedented system affords the enantioenriched functionalized primary alcohols (after nabh4 reduction) in high yields and good to excellent enantioselectivities with wide substrate scope in the absence of any acid additive. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, multidisciplinary |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | chiral ferrocene ligands ; organic-reactions ; homogeneous catalysis ; bond formations ; aqueous-media ; water ; organocatalysis ; indoles ; solvent ; pathway |
| 收录类别 | SCI ; CCR |
| 语种 | 英语 |
| WOS记录号 | WOS:000301354400024 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143162]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Nanyang Technol Univ, Sch Phys & Math Sci, Div Chem & Biol Chem, Singapore 637371, Singapore 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Jian,Zhao, Kai,Loh, Teck-Peng. The acid free asymmetric intermolecular alpha-alkylation of aldehydes in fluorinated alcohols[J]. chemical communications,2012,48(29):3548-3550. |
| APA | Xiao, Jian,Zhao, Kai,&Loh, Teck-Peng.(2012).The acid free asymmetric intermolecular alpha-alkylation of aldehydes in fluorinated alcohols.chemical communications,48(29),3548-3550. |
| MLA | Xiao, Jian,et al."The acid free asymmetric intermolecular alpha-alkylation of aldehydes in fluorinated alcohols".chemical communications 48.29(2012):3548-3550. |
入库方式： OAI收割
来源：大连化学物理研究所
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