Heat capacities and thermodynamic properties of M(HBTC)(4,4 '-bipy)center dot 3DMF (M = Ni and Co)
文献类型：期刊论文
| 作者 | Zhou, Yi-Xi1,2; Sun, Li-Xian2; Cao, Zhong1; Zhang, Jian2; Xu, Fen3; Song, Li-Fang2; Zhao, Zi-Ming2; Zou, Yong-Jin2 |
| 刊名 | journal of thermal analysis and calorimetry
 |
| 出版日期 | 2012-11-01 |
| 卷号 | 110期号:2页码:949-954 |
| 关键词 | Metal-organic framework Molar heat capacity TGA TMDSC |
| 英文摘要 | two metal-organic frameworks (mofs) of m(hbtc)(4,4'-bipy)center dot 3dmf [m = ni (for 1) and co (for 2); h3btc = 1,3,5-benzenetricarboxylic acid (1,3,5-btc); 4,4'-bipy = 4,4'-bipyridine; dmf = n,n'-dimethylformamide] were synthesized by a one-pot solution reaction and a solvothermal method, respectively, and characterized by powder x-ray diffraction and ft-ir spectra. the low-temperature molar heat capacities of m(hbtc)(4,4'-bipy)center dot 3dmf were measured by temperature-modulated differential scanning calorimetry (tmdsc) for the first time. the thermodynamic parameters such as entropy and enthalpy relative to reference temperature 298.15 k were derived based on the above molar heat capacity data. moreover, the thermal stability and the decomposition mechanism of m(hbtc)(4,4'-bipy)center dot 3dmf were investigated by thermogravimetry analysis (tga). the experimental results through tga measurement demonstrate that both of the two compounds have a three-stage mass loss in air flow. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | chemistry, analytical ; chemistry, physical |
| 研究领域[WOS] | chemistry |
| 关键词[WOS] | metal-organic frameworks ; temperature ; storage ; dsc |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000310543000057 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143164]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Changsha Univ Sci & Technol, Sch Chem & Biol Engn, Changsha 410004, Hunan, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Mat & Thermochem Lab, Dalian 116023, Peoples R China 3.Liaoning Normal Univ, Fac Chem & Chem Engn, Dalian 116029, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhou, Yi-Xi,Sun, Li-Xian,Cao, Zhong,et al. Heat capacities and thermodynamic properties of M(HBTC)(4,4 '-bipy)center dot 3DMF (M = Ni and Co)[J]. journal of thermal analysis and calorimetry,2012,110(2):949-954. |
| APA | Zhou, Yi-Xi.,Sun, Li-Xian.,Cao, Zhong.,Zhang, Jian.,Xu, Fen.,...&Zou, Yong-Jin.(2012).Heat capacities and thermodynamic properties of M(HBTC)(4,4 '-bipy)center dot 3DMF (M = Ni and Co).journal of thermal analysis and calorimetry,110(2),949-954. |
| MLA | Zhou, Yi-Xi,et al."Heat capacities and thermodynamic properties of M(HBTC)(4,4 '-bipy)center dot 3DMF (M = Ni and Co)".journal of thermal analysis and calorimetry 110.2(2012):949-954. |
入库方式： OAI收割
来源：大连化学物理研究所
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