Zinc-nickel single flow batteries with improved cycling stability by eliminating zinc accumulation on the negative electrode
文献类型：期刊论文
| 作者 | Cheng, Yuanhui1,2; Lai, Qinzhi1; Li, Xianfeng1; Xi, Xiaoli1,2; Zheng, Qiong1; Ding, Cong1,2; Zhang, Huamin1 |
| 刊名 | electrochimica acta
 |
| 出版日期 | 2014-11-01 |
| 卷号 | 145页码:109-115 |
| 关键词 | Batteries Coulombic efficiency Cycling stability Parasitic reactions Zinc accumulation |
| 英文摘要 | zinc accumulation is recognized as one of the most critical issues that affect the cycle life of zinc-nickel single flow batteries (znbs). in this paper, a novel and very specific method has been proposed to solve the above problem. the side reactions, which are always regarded as negative factors, are promoted at negative side to balance the side reactions at positive side. a novel electrode with high reaction area and well mass transport structure has been designed to facilitate parasitic reactions at negative side. the result shows that zinc accumulation has been successfully solved by balancing positive reactions and negative reactions with this novel electrode, and no zinc accumulates on the negative electrode over 400 cycles. this paper provides an effective way to improve the cycling stability of znbs, which is the most troublesome for the commercialization of znbs. (c) 2014 elsevier ltd. all rights reserved. |
| WOS标题词 | science & technology ; physical sciences |
| 类目[WOS] | electrochemistry |
| 研究领域[WOS] | electrochemistry |
| 关键词[WOS] | hydroxide electrode ; xps characterization ; alkaline-solution ; oxygen evolution ; energy-storage ; oxide ; deposition ; morphology ; metal ; transition |
| 收录类别 | SCI |
| 语种 | 英语 |
| WOS记录号 | WOS:000344203900013 |
| 公开日期 | 2015-11-17 |
| 源URL | [http://159.226.238.44/handle/321008/143208]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| 推荐引用方式 GB/T 7714 | Cheng, Yuanhui,Lai, Qinzhi,Li, Xianfeng,et al. Zinc-nickel single flow batteries with improved cycling stability by eliminating zinc accumulation on the negative electrode[J]. electrochimica acta,2014,145:109-115. |
| APA | Cheng, Yuanhui.,Lai, Qinzhi.,Li, Xianfeng.,Xi, Xiaoli.,Zheng, Qiong.,...&Zhang, Huamin.(2014).Zinc-nickel single flow batteries with improved cycling stability by eliminating zinc accumulation on the negative electrode.electrochimica acta,145,109-115. |
| MLA | Cheng, Yuanhui,et al."Zinc-nickel single flow batteries with improved cycling stability by eliminating zinc accumulation on the negative electrode".electrochimica acta 145(2014):109-115. |
入库方式： OAI收割
来源：大连化学物理研究所
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